Classical model for closed-loop diagrams of binary liquid mixtures

机译：二元液体混合物闭环图的经典模型

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A classical lattice model for closed-loop temperature-composition phase diagrams has been developed. It considers the effect of specific interactions, such as hydrogen bonding, between dissimilar components. This van Laar-type model includes a Flory-Huggins term for the excess entropy of mixing. It is applied to several liquid-liquid equilibria of nonelectrolytes, where the molecules of the two components differ in size. The model is able to represent the observed data semi-quantitatively, but in most cases it is not flexible enough to predict all parts of the closed loop quantitatively. The ability of the model to represent different binary systems is discussed. Finally, attention is given to a correction term, concerning the effect of concentration fluctuations near the upper critical solution temperature.

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Schnitzler, J; Prausnitz, J M;
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年度 1994
页码 1-25
总页数 25
原文格式 PDF
正文语种 eng
中图分类工业技术;
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EDB/400201;

机译：EDB / 400201;

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机译：二元液体混合物闭环图的经典模型

Classical model for closed-loop diagrams of binary liquid mixtures

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