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Configuration of a pulse radiolysis system for the study of gas-phase reactions and kinetic investigations of the reactions of hydroxyl radicals with methyl and ethyl radicals

机译：配置脉冲辐解系统用于研究气相反应和羟基自由基与甲基和乙基自由基反应的动力学研究

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The work that is presented in this thesis deals with the assembling and testing of a pulse radiolysis system for kinetic studies of gas-phase reactions as well as with the kinetics of the gas-phase reactions of hydroxyl radicals with methyl and ethyl radicals. These radicals are very important as these are formed at an early stage in hydrocarbon combustion processes. The two studied reactions are key reactions in those processes. (6 refs., 4 figs., 2 tabs.). (Atomindex citation 24:060743)

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Fagerstroem, K;
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年度 1993
页码 1-24
总页数 24
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Foreign technology; Hydroxyl radicals; EDB/400600; Theses;

机译：国外技术;羟基自由基; EDB / 400600;论文;

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专利

1. Radical intermediates generated in the reactions of L-arginine with hydroxyl radical and sulfate radical anion:A pulse radiolysis study [J] . Takeo Ito, Shota Morimoto, Shin-ichi Fujita Radiation Physics and Chemistry . 2009,第4期

机译：L-精氨酸与羟基自由基和硫酸根自由基阴离子反应生成的自由基中间体：脉冲辐解研究
2. FTIR gas-phase kinetic study on the reactions of OH radicals and Cl atoms with unsaturated esters: Methyl-3,3-dimethyl acrylate, (E)-ethyl tiglate and methyl-3-butenoate [J] . Juan P. Colomer, Maria B. Blanco, Alicia B. Penenory, Atmospheric environment . 2013,第nova期

机译：FTIR气相动力学研究OH自由基和Cl原子与不饱和酯：3,3-甲基丙烯酸二甲酯，（E）-钛酸乙酯和3-丁烯酸甲酯的反应
3. Gas-phase oxidation of methyl crotonate and ethyl crotonate. Kinetic study of their reactions toward oh radicals and Cl atoms [J] . Teruel M.A., Benitez-Villalba J., Caballero N., The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2012,第24期

机译：气相氧化巴豆酸甲酯和巴豆酸乙酯。它们对oh自由基和Cl原子反应的动力学研究
4. Pulse radiolysis study on reaction kinetics and pK_a value of hydroxyl radical at high temperatures [C] . Yusa MUROYA, Hiroyuki TAKAHASHI, Yosuke KATSUMURA, Symposium on Water Chemistry and Corrosion in Nuclear Power Plants in Asia . 2009

机译：脉冲放射性研究高温下羟基的反应动力学和PK_A值
5. PULSE RADIOLYSIS AND AB INITIO SCF MO STUDIES OF HYDROXYL RADICAL REACTIONS WITH 2,2'-BIPYRIDINE AND ITS COMPLEXES WITH TRANSITION METAL IONS (ORBITAL). [D] . MALIYACKEL, ANTHONY CHERU. 1984

机译：2,2'-联吡啶及其与过渡金属离子（轨道）配合物的羟自由基反应的脉冲辐射和从头算。
6. Reversible Hydrogen Transfer Reactions in Thiyl Radicals From Cysteine and Related Molecules: Absolute Kinetics and Equilibrium Constants Determined by Pulse Radiolysis [O] . Thomas Nauser, Willem H. Koppenol, Christian Schöneich -1

机译：在生成硫中心自由基从半胱氨酸及其相关分子的可逆氢转移反应：绝对动力学和平衡常数脉冲辐测定
7. A pulse radiolysis study on the reactions of hydroxyl radical and sulfate radical anion with guanidine derivatives in aqueous solution [O] . Morimoto Shota, Ito Takeo, Fujita Shin-ichi, 2008

机译：水溶液中羟基自由基和硫酸根自由基阴离子与胍衍生物反应的脉冲辐照研究

Configuration of a pulse radiolysis system for the study of gas-phase reactions and kinetic investigations of the reactions of hydroxyl radicals with methyl and ethyl radicals

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