首页> 美国政府科技报告 >CORRELATION OF PHYSICAL PROPERTIES WITH MOLECULAR STRUCTURE FOR DICYCLIC HYDROCARBONS I - 2-n-ALKYLBIPHENYL, 1,1-DIPHENYLALKANE, α, ω-DIPHENYLALKANK 1,1-DICYCLOHEXYLALKANE, ANDα, ω-DICYCLOHEXYLALKANE SERIES
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CORRELATION OF PHYSICAL PROPERTIES WITH MOLECULAR STRUCTURE FOR DICYCLIC HYDROCARBONS I - 2-n-ALKYLBIPHENYL, 1,1-DIPHENYLALKANE, α, ω-DIPHENYLALKANK 1,1-DICYCLOHEXYLALKANE, ANDα, ω-DICYCLOHEXYLALKANE SERIES

机译:双环烃的物理性质与分子结构的相关性I - 2-n-aLKYLBIpENYL,1,1-二苯基烷,α,ω-二苯基烷基1,1-二环己基烷,和α,ω-二环己基烷系列

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摘要

As part of a program to study the correlation between molecular-structure and physical properties of high-density hydrocarbons, the net heat of combustion, melting point, boiling point, density, and kinematic viscosity of some hydrocarbons in the 2-n-alkylbiphenyl, 1,1-diphenylalkane, a,w-diphenylalkane, 1,1-dicyclohexylalkane, and a,u)-dicyclohexylalkane series are presented. Comparisons are made on three bases:n1. As members of an homologous series in which the compounds have similar structures and differ in molecular weight.n2. As isomers with the same molecular weight and molecular formula but different molecular structure.n3. As compounds with the same carbon skeleton but different molecular formula due to hydrogenation of the aromatic rings.

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