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Thermodynamic Properties of Strongly Nonideal Fluid Mixtures from an Extended Quasi-Chemical Theory

机译：从扩展的准化学理论看强非理想流体混合物的热力学性质

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In his later years, E.A. Guggenheim recognized that the exchange energy in his quasi-chemical theory of mixtures is really a free energy. Proper use of quasi-chemical theory contains an entropic contribution which must also be considered in calculating deviations from random mixing. Methods for including this entropic contribution are discussed here. When Guggenheim's quasi-chemical theory is coupled with a two-fluid theory of mixtures and a suitable reference system, we obtain an equation of state that may be particularly useful for fluid mixtures showing large deviations from ideality. (ERA citation 08:012792)

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作者
Dimitrelis, D.; Prausnitz, J. M.;
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年度 1982
页码 1-27
总页数 27
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Mixtures; Fluids; Thermodynamic properties; Liquids; Equations of state; Binary mixtures;

机译：混合物;流体;热力学性质;液体;状态方程;二元混合物;

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专利

1. Quasi-Chemical PC-SAFT: An Extended Perturbed Chain-Statistical Associating Fluid Theory for Lattice-Fluid Mixtures [J] . Khalil Parvaneh, Alireza Shariati The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2017,第35期

机译：准化工PC-SAFT：晶格流体混合物的延伸的扰动链统计关联流体理论
2. THERMODYNAMIC PROPERTIES OF TERNARY FLUID MIXTURES FROM THE IMPROVED PERTURBATION THEORY AND VAN DER WAALS ONE-FLUID THEORY .2. REAL MIXTURES [J] . Fotouh K., Shukla K. Chemical Engineering Science . 1996,第21期

机译：改进的扰动理论和范德华一流体理论的三元流体热力学性质。2。真正的混合物
3. THERMODYNAMIC PROPERTIES OF TERNARY FLUID MIXTURES FROM THE IMPROVED PERTURBATION THEORY AND VAN DER WAALS ONE-FLUID THEORY .1. MODEL MIXTURES [J] . Fotouh K., Shukla K. Chemical Engineering Science . 1996,第21期

机译：改进的扰动理论和范德华一流体理论的三元混合物热力学性质1。模型混合
4. Modelling of CO2/acetone fluid mixture thermodynamic properties for compression/resorption refrigeration systems [C] . R J B Moreira-da-Silva, D Salavera, A Coronas National Conference on Thermodynamics with International Participation . 2019

机译：CO2 /丙酮流体混合物对压缩/吸收制冷系统的热力学性能建模
5. Prediction of bulk and interfacial thermodynamic properties of polar mixtures by statistical associating fluid theory. [D] . Ayyalasomayajula, Padmakar S. 2003

机译：通过统计关联流体理论预测极性混合物的体积和界面热力学性质。
6. Two-fluid theory and thermodynamic properties of liquid mixtures. Application to hard-sphere mixtures [O] . V. Brandani, J. M. Prausnitz 1982

机译：双重流体理论和液体混合物的热力学性质。适用于硬球混合物
7. On the calculation of equilibrium thermodynamic properties and the establishment of statistical-thermodynamically-consistent finite bound-state partition functions in nonideal multi-component plasma mixtures within the chemical model [O] . Zaghloul, Mofreh R. 2010

机译：关于平衡热力学性质的计算及其建立统计 - 热力学一致的有限约束状态在非理想的多组分等离子体混合物中的分配功能化学模型
8. Ebulliometers for measuring the thermodynamic properties of fluids and fluid mixtures [R] . Weber, L. A. , Silva, A. M. 1994

机译：用于测量流体和流体混合物的热力学性质的沸点计

Thermodynamic Properties of Strongly Nonideal Fluid Mixtures from an Extended Quasi-Chemical Theory

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