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Synthesis and characterization of two oxo-bridged oxo(arylimido) tris(3,5-dimethylpyrazolyI)boratomolybdenum(V) complexes and crystal structure of MoTp(O)CI(μ-O)MoTp(CI)(≡NC6H 4OMe)

机译：两种氧桥联氧代（芳基酰亚胺）三（3,5-二甲基吡唑基I）硼酸酯钼（V）配合物的合成和表征以及MoTp *（O）CI（μ-O）MoTp *（CI）的晶体结构）（≡NC6H4OMe）

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Reaction of the oxo-molybdenum(V) compound, [MoTp*(O)Cl2], [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate] with p-methoxy and p-nitroaniline in the presence of Et3N under N2, afforded the oxo-bridged oxo(arylimido) molybdenum(V) complexes, [MoTp*(O)Cl](μ- O)[MoTp*(Cl)(≡NC6H4R)] (1, R = OMe; 2, R = NO2). The new compounds were characterized by elemental analysis, i.r., mass, and 1H-n.m.r. spectra. The single crystal X-ray crystallographic determination of [MoTp*(O)Cl](μ-O)[MoTp*(Cl) (≡NC6H4OMe)] was carried out to confirm that there is a Mo - O - Mo bridge and a near linear arylimido group in the structure.

机译：含氧钼（V）化合物[MoTp *（O）Cl2]，[Tp * =氢三（3,5-二甲基吡唑-1-基）硼酸酯]与对甲氧基和对硝基苯胺的反应在氮气下，用Et3N制备羰基桥联的氧代（芳基酰亚胺）钼（V）配合物，[MoTp *（O）Cl]（μ-O）[MoTp *（Cl）（≡NC6H4R）]（1，R = OMe; 2，R = NO2）。通过元素分析，即质量和1H-n.m.r对新化合物进行表征。光谱。对[MoTp *（O）Cl]（μ-O）[MoTp *（Cl）（≡NC6H4OMe）]进行单晶X射线晶体学测定，以确认存在一个Mo-O-Mo桥和一个在结构中接近线性芳基基团。

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Topaloğlu Işıl; Günyar Alev; Jeffery John C.; Hamidov Hayrullah;
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年度 2004
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机译：两种含氧桥联的氧代（芳基酰亚胺）[三（3,5-二甲基吡唑基）硼酸酯]钼（V）配合物的合成和晶体结构[MoTp〜*（O）Cl]（mu-O）IMoTp〜*（ Cl）（（与NC_6H_4OMe相同）]
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Synthesis and characterization of two oxo-bridged oxo(arylimido) tris(3,5-dimethylpyrazolyI)boratomolybdenum(V) complexes and crystal structure of MoTp*(O)CI(μ-O)MoTp*(CI)(≡NC6H 4OMe)

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Synthesis and characterization of two oxo-bridged oxo(arylimido) tris(3,5-dimethylpyrazolyI)boratomolybdenum(V) complexes and crystal structure of MoTp(O)CI(μ-O)MoTp(CI)(≡NC6H 4OMe)