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Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II)

机译：铑（III）和铂（II）的三氯锡锡配合物的电子光谱和光化学

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The absorption spectra of [Rh(SnCl3)4Cl2]3− and [Pt(SnCl3)5]3− are characterized by a similar band pattern. It is suggested that the absorption spectra are dominated by bands which are assigned to intraligand transitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature emission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient photosubstitution of the trichlorostannyl ligand.

机译：[Rh（SnCl3）4Cl2] 3-和[Pt（SnCl3）5] 3-的吸收光谱具有相似的能带图。建议吸收光谱由分配给配体内跃迁的带支配。固体（NBu4）3 [Pt（SnCl3）5]显示低温发射，但铑配合物不发光。两种络合物阴离子在乙腈溶液中均对光敏感。它们经历三氯锡烷基配体的有效光解。

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Pawlowski V.; Kunkely Horst; Vogler Arnd;
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年度 1994
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正文语种 {"code":"en","name":"English","id":9}
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Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II)

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