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Electrochemical study of nickel(salen) and cobalt(salen) derivatives complexes in the presence of unsaturated halides

机译:不饱和卤化物存在下镍(salen)和钴(salen)衍生物配合物的电化学研究

摘要

The electrochemical intramolecular cyclisation of allyl 2-bromophenyl ethers in N,N'-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni(II) and Co(II) complexes as electron-transfer mediators. Cyclic compounds are obtained in good yields under appropriate experimental conditions.
机译:使用Ni(II)和Co(II)配合物作为电子转移介体,在无隔膜电池中以恒定电流在N,N'-二甲基甲酰胺中对烯丙基2-溴苯基醚进行电化学分子内环化反应。在适当的实验条件下以高收率获得环状化合物。

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