首页> 外国专利> SUBSTRATE CONTAINING ALUMINUM WITH AT LEAST ONE MICROPOROUS LAYER APPLIED SUPERFICIALLY FROM AN ALUMINUM PHOSPHATE ZEOLITE (ALPO) AND OTHER LAYERS, PROCESS FOR ITS PREPARATION AND EMPLOYMENT

SUBSTRATE CONTAINING ALUMINUM WITH AT LEAST ONE MICROPOROUS LAYER APPLIED SUPERFICIALLY FROM AN ALUMINUM PHOSPHATE ZEOLITE (ALPO) AND OTHER LAYERS, PROCESS FOR ITS PREPARATION AND EMPLOYMENT

机译:包含铝的基质,至少要从磷酸铝沸石(ALPO)和其他层上至少涂覆一层微孔层,以进行制备和使用

摘要

substrate containing aluminum with at least one microporous layer applied superficially from an aluminum phosphate zeolite (alpo) and other layers, process for its preparation and use thereof the present invention refers to a substrate containing aluminum with at least one microporous layer aluminum phosphate zeolite (alpo) and other superficially applied layers. this aluminum-containing substrate is characterized by the fact that the microporous layer of the aluminum phosphate zeolite has a primary layer, on which there is a secondary microporous or mesoporous material different from that of the primary layer. this aluminum-containing substrate is very advantageously prepared according to a process in which: 1. a substrate containing aluminum in a hydrothermally treated aqueous suspension comprising at least one phosphorus as a crosslinking element and on which, through in situ crystallization, a microporous primary layer of an aluminum phosphate zeolite is formed, in particular the molar ratio of cross-forming aluminum, deficiently present in the aqueous suspension, for the sum of all cross-forming elements present in the aqueous suspension, is below 0.5, so that the aluminum required to compensate for the deficiency is removed from the substrate containing aluminum, and that 2. a secondary microporous or mesoporous material is formed on the primary microporous layer, such that the primary porous layer presenting the substrate containing aluminum is subjected to another treatment in an aqueous suspension, which contains the necessary crosslinking elements for the formation of the porous secondary material. the substrate containing the aluminum described is especially suitable as a heat exchanger, as a catalytic reactor or as a constructive element in heat exchanger technology with anti-corrosion effect or anti-fouling effect.
机译:包含铝的基质,其具有至少一个由磷酸铝沸石(alpo)和其他层表面涂覆的微孔层,其制备方法和用途本发明涉及包含铝的基质,该基质具有至少一个微孔层的磷酸铝沸石(alpo) )和其他表面施加的层。该含铝基材的特征在于,磷酸铝沸石的微孔层具有第一层,在其上存在与第一层不同的第二微孔或中孔材料。该含铝基质可非常有利地根据以下方法制备:1.在水热处理的水悬浮液中将铝包含在基质中,该悬浮液包含至少一种磷作为交联元素,并通过原位结晶在其上形成微孔底层形成一种磷酸铝沸石,特别是对于水悬浮液中存在的所有交联元素的总和而言,在水悬浮液中不足的交联铝的摩尔比低于0.5,因此所需的铝为了补偿该缺陷,从含铝的基底上除去,并且在次级微孔层上形成第二微孔或中孔材料,使得呈现含铝的基底的初级多孔层在水溶液中进行另一处理。悬浮液,其中包含形成多孔仲醇所必需的交联元素原始材料。含有铝的基材特别适合用作热交换器,催化反应器或热交换器技术中具有防腐蚀或防污作用的结构元件。

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