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METHOD OF FABRICATING HIGH CONDUCTIVE POLYANILINE AND HIGH CONDUCTIVE POLYANILINE MANUFACTURED THEREBY

机译:制造高导电性聚苯胺的方法及其制造的高导电性聚苯胺

摘要

There is provided a process for producing a highly conductive polyaniline and a highly conductive polyaniline produced thereby. Specifically, the method includes the steps of mixing an organic solvent, an organic acid, and an aniline monomer to form an organic mixed solution, adding a solid oxidizing agent to the organic mixed solution to perform a polymerization reaction, filtering the polymerized polymerization product, , Dedoping the washed product to form a precipitate, and washing and drying the undoped precipitate to obtain a polyaniline polymer. Accordingly, the present invention can synthesize a polymer having a linear structure as the reaction proceeds at a solid / liquid interface due to the solid-state oxidizing agent and the reaction rate is slowed down. Further, by adding an organic acid, the polymer produced by the polymerization reaction can be easily dissolved in an organic solvent without aggregation or precipitation. In addition, it is possible to synthesize highly conductive polyaniline at room temperature, thereby improving the convenience of the manufacturing process.
机译:提供了一种用于生产高导电性聚苯胺的方法以及由此生产的高导电性聚苯胺。具体地,该方法包括以下步骤:混合有机溶剂,有机酸和苯胺单体以形成有机混合溶液,向该有机混合溶液中加入固体氧化剂以进行聚合反应,过滤聚合的聚合产物, ,将洗涤产物去掺杂以形成沉淀,然后洗涤并干燥未掺杂的沉淀以获得聚苯胺聚合物。因此,由于固态氧化剂,当反应在固/液界面进行时,本发明可以合成具有线性结构的聚合物,并且反应速度减慢。此外,通过添加有机酸,由聚合反应产生的聚合物可以容易地溶解在有机溶剂中而不会发生聚集或沉淀。另外,可以在室温下合成高导电性聚苯胺,从而提高了制造工艺的便利性。

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