首页> 外国专利> Processes for preparing a silicon material mesoporoso, a composite silicon, an inorganic material mesoporoso and a composite inorganic / organic order nemu00e1tica chiral, silicon material mesoporoso, composite material, inorganic silicon chiral, mesoporoso with order nemu00e1tica qui Ral, inorganic / organic composite, and article

Processes for preparing a silicon material mesoporoso, a composite silicon, an inorganic material mesoporoso and a composite inorganic / organic order nemu00e1tica chiral, silicon material mesoporoso, composite material, inorganic silicon chiral, mesoporoso with order nemu00e1tica qui Ral, inorganic / organic composite, and article

机译:制备硅材料中孔,复合硅,无机材料中孔和复合无机/有机有序手性,硅材料中孔,复合材料,无机硅手性,介孔有序的中孔的方法,无机 /有机复合物,及文章

摘要

Processes for preparing a silicon material mesoporoso, a composite silicon, an inorganic material mesoporoso and a composite inorganic / organic order nemu00e1tica chiral, silicon material mesoporoso, composite material, inorganic silicon chiral, mesoporoso with order nemu00e1tica qui Ral, inorganic / organic composite, and article.This invention describes a composition and a method for producing materials mesoporosos silica with a chiral organization. In the method, a polymerisable monomer is reacted in the presence of inorganic Nanocrystalline Cellulose (NNC) to provide a solid inorganic material with cellulose nanocrystals embedded in an organization nemu00e1tica chiral.The NCC can be removed to provide a stable porous structure that maintains the chiral organization of mould of NCC. The new materials can be obtained as independent films iridescent with large surface area. By controlling the reaction conditions, the color of the films can be varied throughout the visible spectrum.These are the first materials to combine the mesoporosidade with long range chiral order, which leads to the photonic properties.Examples of possible applications of the materials are: reinforcing materials of light weight materials with low k dielectric reflective tunable filters, adsorbents, stationary phases for chromatography of chiral substances or non chiral, supports for catalysts (for example, P. For asymmetric synthetic transformations).And as a mold to generate other new porous materials (for example, porous carbon or metal porous), preferably with nemu00e1ticas chiral structures.
机译:制备硅材料中孔,复合硅,无机材料中孔和复合无机/有机有序手性,硅材料中孔,复合材料,无机硅手性,中性有序的中孔的方法,无机有机复合物和制品。本发明描述了用于制备具有手性组织的中孔二氧化硅的组合物和方法。在该方法中,可聚合单体在无机纳米晶体纤维素(NNC)存在下进行反应,以提供一种固体无机材料,其中纤维素纳米晶体嵌入了手性手性组织中。可以去除NCC以提供一种稳定的多孔结构,以保持NCC霉菌的手性组织。可以将新材料制成具有大表面积的呈虹彩的独立膜。通过控制反应条件,可以在整个可见光谱范围内改变薄膜的颜色,这是第一种将介孔孢子与长距离手性相结合的材料,具有光子学性质。轻质材料的增强材料,具有低k介电反射可调滤光片,吸附剂,用于手性物质色谱或非手性色谱的固定相,用于催化剂的载体(例如,P。用于不对称合成转化)。多孔材料(例如,多孔碳或多孔金属),最好具有nem u00e1ticas手性结构。

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