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Method for manufacturing photoelectrode for quantum dot-sensitized solar cell

机译:用于量子点敏化太阳能电池的光电极的制造方法

摘要

PROBLEM TO BE SOLVED: To provide a method for manufacturing a photoelectrode for quantum dot sensitized solar batteries by which a long-chain alkyl group which inevitably sticks to a quantum dot can be removed for a short time, and a photoelectrode arranged so that reverse electron transfer from a quantum dot can be suppressed can be manufactured with good productivity.SOLUTION: A method for manufacturing a photoelectrode for quantum dot sensitized solar batteries which is to be arranged opposite to a counter electrode through an electrolytic layer comprises the steps of: forming a transparent electrode layer 21 on a surface of a substrate 1; forming, on a surface of the transparent electrode layer 21, a semiconductor layer 22 which performs a photoelectric conversion; causing quantum dots 23 to be adsorbed onto a surface of the semiconductor layer by immersing the substrate in a fluid dispersion with the quantum dots distributed therein; substituting sulfur for ligands inevitably sticking to the quantum dots when causing the quantum dot adsorption by immersing the substrate in a liquid solution containing sulfide ions; and forming, on surfaces of the quantum dots and the semiconductor layer, a buffer layer 24 for preventing electrons from flowing into the electrolytic layer.
机译:解决的问题:提供一种用于量子点敏化太阳能电池的光电极的制造方法,通过该方法可以在短时间内去除不可避免地粘附在量子点上的长链烷基,并排列光电极以使电子反向解决方案:一种用于制造量子点敏化太阳能电池的光电极的方法,该光电极通过电解质层与对电极相对布置,该方法包括以下步骤:基板1的表面上的透明电极层21。在透明电极层21的表面上形成进行光电转换的半导体层22;通过将基板浸入其中分散有量子点的流体分散体中,使量子点23被吸附到半导体层的表面上;当通过将衬底浸入含有硫化物离子的液体溶液中引起量子点吸附时,用硫代替配体不可避免地粘附在量子点上;在量子点和半导体层的表面上形成缓冲层24,该缓冲层24用于防止电子流入电解质层。

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