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PERIPHERALLY AROMATIC SILSESQUIOXANES FEATURING REACTIVE FUNCTIONALITY: SYNTHESIS AND APPLICATION THEREOF

机译:具有反应功能的外围芳香型硅倍半氧杂环丁烷:合成及其应用

摘要

Methods of synthesis and application thereof for peripherally aromatic silsesquioxanes featuring reactive functionality. A method, according to one embodiment of the invention, includes reacting a polyhedral oligomeric silsesquioxane with an anhydride. The polyhedral oligomeric silsesquioxane has an inorganic core, a phenyl moiety or an anlyine moiety covalently coupled to the at least one T-type silicon atom; and a metal-aniline group or a para-aniline group covalently coupled to the at least one D-type or M-type silicon atom. The inorganic core includes 6-14 silicon atoms, at least one of the silicon atoms being an M-type silicon atom or a D-type silicon atom, and at least one of the silicon atoms being a T-type silicon atom, and 9-20 oxygen atoms
机译:具有反应性官能团的外围芳族倍半硅氧烷的合成方法及其应用。根据本发明的一个实施方案,一种方法包括使多面体低聚倍半硅氧烷与酸酐反应。多面体低聚倍半硅氧烷具有与至少一个T型硅原子共价偶联的无机核,苯基部分或an基部分。与所述至少一个D型或M型硅原子共价结合的金属苯胺基或对苯胺基。无机核包括6-14个硅原子,其中至少一个硅原子是M型硅原子或D型硅原子,并且至少一个硅原子是T型硅原子,和9 -20个氧原子

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