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FUNCTIONALIZATION OF ORGANIC MOLECULES USING METAL-ORGANIC FRAMEWORKS (MOFS) AS CATALYSTS

机译:以金属有机骨架(MOFS)为催化剂的有机分子功能化

摘要

1. A method of replacing at least one atom of an organic molecule with another atom or group of atoms, by contacting the molecule with Organometallic strukturoy.2. A method according to Claim. 1, wherein the organic molecule is a uglevodorod.3. A method according to Claim. 1, wherein the hydrogen in the organic molecule is replaced by an oxygen-containing functional gruppoy.4. A method according to Claim. 1, wherein the method is carried out in the presence CO.5. A method according to Claim. 1, wherein the method is carried out in the presence okislitelya.6. A method according to Claim. 1, wherein the organic molecule is an alkane, which is converted to a carboxylic kislotu.7. A method according to Claim. 1, wherein the organometallic structure comprises a metal or metal ion including alkali metal, alkaline earth metal, transition metal, lanthanide, actinide, metalloid, or post-transition metall.8. . A method according to claim 7, wherein the organometallic structure comprises a metal or metal ion selected from the group consisting of: Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Sc, Sc, Sc, Y , Y, Y, Ti, Ti, Ti, Zr, Zr, Zr, Hf, Hf, V, V, V, V, Nb, Nb, Nb, Nb, Ta, Ta, Ta, Ta, Cr, Cr, Cr , Cr, Cr, Cr, Cr, Mo, Mo, Mo, Mo, Mo, Mo, Mo, W, W, W, W, W, W, W, Mn, Mn, Mn, Mn, Mn, Mn, Mn , Re, Re, Re, Re, Re, Re, Re, Re, Fe, Fe, Fe, Fe, Fe, Fe, Ru, Ru, Ru, Ru, Ru, Ru, Os, Os, Os, Os, Os , Os, Os, Os, Os, Co, Co, Co, Co, Co, Rh, Rh, Rh, Rh, Rh, Rh, Ir, Ir, Ir, Ir, Ir, Ir, Ir, Ni, Ni, Ni , Ni, Pd, Pd, Pd, Pd, Pd, Pt, Pt. Pt, Pt, Pt, Pt, Cu, Cu, Cu, Cu, Ag, Ag, Ag, Au, Au, Au, Au, Au, Zn, Zn, Zn, Cd, Cd, Hg, Hg, Hg, B, B, B, Al, Al, Al, Ga, Ga, Ga, In, In, In, Tl, Tl, Si, Si, Si, Si, Ge, Ge, Ge, Ge, Ge, Sn, Sn, Pb, Pb, As, As, As, As, Sb, Sb, Bi, Bi, Te, Te, Te, Te, La, La, Ce, Ce, Ce, Pr, Pr, Pr, Nd, Nd, Sm, Sm, eu, eu, Gd, Gd, Gd, Tb, Tb, Tb, Tb, Dy, Dy, Ho, Er, Tm, Tm, Tm, Yb, Ybi Lu.9. A method according to Claim. 1, wherein the organometallic structure comprises a metal or metal ion having a molecular geometry selected from the group consisting of planar trigonal, tetrahedral, square planar, trigonal
机译:1.一种使有机分子中的至少一个原子与另一原子或原子团置换的方法,方法是使该分子与有机金属结构接触。根据权利要求1的方法。 1,其中有机分子是uglevodorod。3。根据权利要求1的方法。 1,其中有机分子中的氢被含氧官能团取代4。根据权利要求1的方法。 1,其中所述方法在CO.5存在下进行。根据权利要求1的方法。 1,其中该方法是在okislitelya.6存在下进行的。根据权利要求1的方法。 1,其中有机分子是烷烃,其被转化成羧酸基7。根据权利要求1的方法。 1,其中有机金属结构包括金属或金属离子,包括碱金属,碱土金属,过渡金属,镧系元素,act系元素,准金属或过渡后金属。8。 。 8.根据权利要求7所述的方法,其中,所述有机金属结构包括选自以下的金属或金属离子:Li,Na,K,Rb,Cs,Be,Mg,Ca,Sr,Ba,Sc,Sc,Sc, Y,Y,Y,Ti,Ti,Ti,Zr,Zr,Zr,Hf,Hf,V,V,V,V,Nb,Nb,Nb,Nb,Ta,Ta,Ta,Ta,Ta,Cr,Cr,铬,铬,铬,铬,铬,钼,钼,钼,钼,钼,钼,钼,钼,钨,钨,钨,钨,钨,钨,锰,锰,锰,锰,锰,锰,锰, Mn,Re,Re,Re,Re,Re,Re,Re,Re,Re,Fe,Fe,Fe,Fe,Fe,Fe,Fe,Ru,Ru,Ru,Ru,Ru,Ru,Ru,Os,Os,Os,Os, Os,Os,Os,Os,Os,Co,Co,Co,Co,Co,Rh,Rh,Rh,Rh,Rh,Rh,Rh,Ir,Ir,Ir,Ir,Ir,Ir,Ir,Ni,Ni,镍,镍,钯,钯,钯,钯,钯,铂,铂Pt,Pt,Pt,Pt,Cu,Cu,Cu,Cu,Cu,Ag,Ag,Ag,Au,Au,Au,Au,Au,Au,Zn,Zn,Zn,Cd,Cd,Hg,Hg,Hg,B, B,B,Al,Al,Al,Ga,Ga,Ga,In,In,In,Tl,Tl,Si,Si,Si,Si,Ge,Ge,Ge,Ge,Ge,Ge,Sn,Sn,Pb, Pb,As,As,As,As,Sb,Sb,Bi,Bi,Te,Te,Te,Te,La,La,Ce,Ce,Ce,Pr,Pr,Pr,Nd,Nd,Sm,Sm, eu,eu,Gd,Gd,Gd,Tb,Tb,Tb,Tb,Dy,Dy,Ho,Er,Tm,Tm,Tm,Yb,Ybi Lu.9。根据权利要求1的方法。参照图1,其中有机金属结构包括分子形状选自平面三角形,四面体,正方形平面,三角形的金属或金属离子

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