首页> 外国专利> METHOD FOR HYDROTHERMAL SYNTHESIS OF A SULFUR-CONTAINING ALUMINOSILICATE WITH A CRYSTALLINE SODALITE STRUCTURE, AND SULFUR-CONTAINING ALUMINOSILICATE AND USE THEREOF

METHOD FOR HYDROTHERMAL SYNTHESIS OF A SULFUR-CONTAINING ALUMINOSILICATE WITH A CRYSTALLINE SODALITE STRUCTURE, AND SULFUR-CONTAINING ALUMINOSILICATE AND USE THEREOF

机译:晶体硅酸钠结构的含硫硅铝酸盐的水热合成方法及其用途

摘要

The invention relates to a method for producing a microporous material for molecular-sieve gas separation of small molecules at high temperatures and in the presence of water. The invention addresses the problem of eliminating the disadvantages of the prior art so that the separation of hydrogen from anhydrous gas mixtures by absorption or membrane separation with porous materials at temperatures up to 800°C, as well as the separation of hydrogen and water at temperatures up to at least 300°C, is possible on a large industrial scale. This problem is solved according to the invention by a method for producing a thermally and hydrothermally particularly stable microporous aluminosilicate (zeolite), which is capable, due to the pores having a diameter of 0.3 nm in its crystalline structure, of separating small gas molecules such as hydrogen, helium and water selectively from gas mixtures by pore absorption or adsorption and permeation at elevated temperatures and in the presence of water.
机译:本发明涉及一种用于在高温和水存在下分离小分子的分子筛气体的微孔材料的制备方法。本发明解决了消除现有技术的缺点的问题,即通过在高达800℃的温度下通过多孔材料的吸收或膜分离从无水气体混合物中分离氢,以及在该温度下分离氢和水。在大规模工业规模中,最高温度可达300°C。根据本发明,通过生产热和水热特别稳定的微孔铝硅酸盐(沸石)的方法解决了该问题,该方法由于其晶体结构中直径小于0.3nm的孔能够分离小气体分子在高温和水的存在下,通过孔隙吸收或吸附和渗透从气体混合物中选择性地除去诸如氢,氦和水之类的氢。

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