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首页> 外国专利> Process for preparation of cyclopropane derivatives of fullerenes, use of organic fullerene derivatives as materials for electronic semiconductor device, organic field-effect transistor, organic photovoltaic cell, organic field-effect transistors and organic photovoltaic cell

Process for preparation of cyclopropane derivatives of fullerenes, use of organic fullerene derivatives as materials for electronic semiconductor device, organic field-effect transistor, organic photovoltaic cell, organic field-effect transistors and organic photovoltaic cell

机译：富勒烯环丙烷衍生物的制备方法，有机富勒烯衍生物用作电子半导体器件，有机场效应晶体管，有机光伏电池，有机场效应晶体管和有机光伏电池的材料

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1. A process for preparing cyclopropane derivatives of fullerenes by heating unmodified fullerene with tosylhydrazone in the presence of a solvent and a base, characterized in that the process is carried out with ether tosylhydrazone ketouksusnoy α-acids of general Formula 1, wherein in the general formula R 1 radical denotes, but is not limited to the following definitions - arbitrarily substituted linear or branched aliphatic radical C, where n ranges from 1 to 50; - arbitrarily substituted linear or branched heteras oalkilny radical C, where n ranges from 1 to 50; - arbitrarily substituted linear or branched unsaturated hydrocarbon C radical, where n ranges from 1 to 50; - arbitrarily substituted cycloalkyl hydrocarbon C radical, where n is in the range from 1 to 50; - arbitrarily substituted heterocycloalkyl hydrocarbon radical C, where n ranges from 1 to 50; - arbitrarily substituted C aralkyl radical, where n ranges from 1 to 50, - wherein in the general formula 1 radical Robo significant, but is not limited to the following definitions: - arbitrarily substituted linear or branched aliphatic C radical, where n ranges from 1 to 50; - arbitrarily substituted linear or branched heteroalkyl radical C, where n ranges from 1 to 50; - arbitrarily substituted linear or branched unsaturated hydrocarbon radical C, where n ranges from 1 to 50; - cycloalkyl arbitrarily substituted with C a hydrocarbon radical, where n ranges from 1 to 5
机译：1.一种通过在溶剂和碱的存在下将未改性的富勒烯与甲苯磺酰heating加热而制备富勒烯的环丙烷衍生物的方法，其特征在于该方法是用通式1的醚甲苯磺酰酮戊二酸α-酸进行的，其中式R 1基团表示但不限于以下定义-任意取代的直链或支链脂族基团C，其中n为1至50; -任意取代的直链或支链杂原子烷基C，其中n为1至50; -任意取代的直链或支链不饱和烃C基团，其中n为1至50; -任意取代的环烷基烃C基团，其中n为1至50; -任意取代的杂环烷基烃基C，其中n为1至50; -任意取代的C芳烷基，其中n为1至50，-其中在通式1中，Robo基团是重要的，但不限于以下定义：-任意取代的直链或支链脂族C基团，其中n为1至50; -任意取代的直链或支链杂烷基C，其中n为1至50; -任意取代的直链或支链不饱和烃基C，其中n为1至50; -被C任意取代的环烷基为烃基，其中n为1-5

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