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HYDROGEN PRODUCTION BY AN AUTOTHERMAL HEAT EXCHANGER PACKED-BED MEMBRANE GAS REFORMER

机译:通过自动换热器袋装床膜式气体重整器生产氢气

摘要

A process for producing hydrogen from natural gas, said process comprises the steps of: (i) providing an autothermal heat exchanger packed-bed membrane reformer (APBMR) comprising: (a) an elongated external gas oxidation compartment comprising an inlet, an outlet and packed oxidation catalyst particles, said inlet and outlet being located each at one extremity of said external gas oxidation compartment; (b) an elongated internal gas steam-reforming compartment comprising an inlet, an outlet and packed steam-reforming catalyst particles, said inlet and outlet being located each at one extremity of said internal gas steam-reforming compartment; (c) one or more hydrogen-separating membrane(s) positioned in said steam-reforming compartment substantially parallel to the longitudinal axis of said steam-reforming compartment; (d) one insulation layer surrounding said external compartment; and, optionally, (e) one or more elongated internal gas oxidation compartment(s) positioned in said steamreforming compartment substantially parallel to the longitudinal axis of said gas steam-reforming internal compartment, and comprising an inlet, an outlet and packed oxidation catalyst particles, said inlet and outlet being located each at an extremity of said internal gas oxidation compartment(s); (ii) supplying a mixture comprising said natural gas and air to said gas oxidation compartment(s) of said reformer; and (iii) supplying a mixture comprising said natural gas and water to said gas steam-reforming compartment, wherein the water-to-gas molar ratio
机译:一种由天然气生产氢气的方法,所述方法包括以下步骤:(i)提供一种自动热交换器填充床膜重整器(APBMR),其包括:(a)细长的外部气体氧化室,其包括入口,出口和填充的氧化催化剂颗粒,所述入口和出口分别位于所述外部气体氧化室的一个末端。 (b)细长的内部气体蒸汽重整室,其包括入口,出口和填充的蒸汽重整催化剂颗粒,所述入口和出口分别位于所述内部气体蒸汽重整室的一个末端; (c)基本上平行于所述蒸汽重整室的纵轴设置在所述蒸汽重整室中的一个或多个氢分离膜; (d)围绕所述外部隔室的一层绝缘层; (e)一个或多个细长的内部气体氧化室,其基本上平行于所述气体蒸汽重整内部室的纵轴设置在所述蒸汽重整室中,并且包括入口,出口和填充的氧化催化剂颗粒,所述入口和出口分别位于所述内部气体氧化室的末端; (ii)向所述重整器的所述气体氧化室供应包含所述天然气和空气的混合物; (iii)将包含所述天然气和水的混合物供应至所述气体蒸汽重整室,其中所述水与气体的摩尔比

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