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Mobility and effects due to surface charge

机译:表面电荷导致的流动性和影响

摘要

PROBLEM TO BE SOLVED: To remove the effect of an electroosmotic flow in a method for measuring the velocity distribution of particles using a capillary cell.;SOLUTION: In a method and an equipment for automatically calculating the charge related characteristics or the charge induced parameters of particles (78) in a dispersion liquid (76) or on the wall of a cell, a dispersion liquid (76) containing particles is fed into a cell (52) and irradiated with light from a light source and a light scattered from the particles is detected in a detection space. The dispersion liquid (76) is applied with an electric field at a first field direction switching frequency and then applied with an electric field at a second field direction switching frequency. A first value related to the velocity distribution of particles is obtained using a signal detected from the light scattered upon application of the electric field at the first frequency. The velocity distribution of particles is corrected using a second velocity related signal or value derived from the light scattered during application of the electric field at the second frequency. The first frequency is low enough to obtain a resolution allowable for the distribution of particle velocity related value.;COPYRIGHT: (C)2002,JPO
机译:解决的问题:在使用毛细管测量颗粒速度分布的方法中消除电渗流的影响;解决方案:在一种自动计算电荷相关特性或电荷诱导参数的方法和设备中在分散液(76)中或在细胞壁上的颗粒(78)中,将包含颗粒的分散液(76)送入细胞(52)中,并用来自光源的光和从颗粒散射的光照射在检测空间中被检测到。向分散液(76)施加第一电场方向切换频率的电场,然后施加第二电场方向切换频率的电场。使用从在以第一频率施加电场时从散射的光中检测到的信号来获得与粒子的速度分布有关的第一值。使用第二速度相关信号或从以第二频率施加电场期间散射的光得出的值来校正粒子的速度分布。第一个频率足够低,以获得可用于粒子速度相关值分布的分辨率。;版权所有:(C)2002,JPO

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