首页> 外国专利> With former cooling-off period control being manner in order resolution the parent ion choice with

With former cooling-off period control being manner in order resolution the parent ion choice with

机译:以以前的冷却周期控制方式来解决母离子的选择

摘要

PURPOSE: To avoid disorder of ion paths and suppress an ultimate ion loss and expansion of the trap size by taking cooling time for ions in ionization process in a quadrupole ion trap to form a high signal-to-noise ratio. ;CONSTITUTION: This method is to selectively dissociate parent ions by collision dissociation in a quadrupole ion trap (hereafter called as a trap) and comprises the following processes (a)-(f): (a) introducing a buffer gas into the trap; (b) injecting a sample gas to be analyzed into the trap; (c) applying at least an RF field with an amplitude V and d.c. potential U to capture ions with a selected mass/charge ratio in a selected stabilized operation mode of the trap; (d) ionizing the sample; (e) continuously carrying out the application of the RF field at selected various time intervals; and (f) adjusting the amplitude V or the potential U to assume the value of the energy from the RF filed to be transmitted non-resonant manner to the selected ions.;COPYRIGHT: (C)1995,JPO
机译:目的:通过在四极离子阱中进行离子化过程中的离子冷却时间以形成高信噪比,避免离子路径混乱并抑制最终离子损失和阱尺寸的扩大。 ;组成:该方法是通过四极离子阱(以下称为阱)中的碰撞解离选择性地分离母体离子,其包括以下过程(a)-(f):(a)将缓冲气体引入阱中; (b)将待分析的样气注入阱中; (c)至少施加振幅为V和d.c的RF场。以陷阱的选定稳定操作模式捕获具有选定质荷比的离子的电势U; (d)电离样品; (e)在选定的各种时间间隔内连续进行射频场的应用; (f)调整幅度V或电势U,以假定来自将要以非共振方式传输到选定离子的RF的能量值。COPYRIGHT:(C)1995,JPO

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