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The metal chelate compound which from monoazo chemical compound and Ni, Co or Cu which

机译:由单偶氮化合物和镍,钴或铜构成的金属螯合物

摘要

PROBLEM TO BE SOLVED: To obtain a metal chelate compound improved in light resistance, storage stability and heat resistance by adding Ni, Co or Cu to a specified monoazo compound. SOLUTION: An amino compound represented by formula I (A is a residue which forms a thiadizole or isoxazole ring together with the C and N to which it is bonded) is diazotized, and the product is reacted with a coupling component represented by formula II (Z1 is a benzene ring which may be substituted or a 1-6C alkyl or branched alkyl which may be substituted; X1 and X2 are each H, an alkyl, an alkoxy or a halogen; E is NY1 Y2 ; and Y1 and Y2 are each an alkyl which may be substituted) to obtain a monoazo compound represented by formula III. A methanolic or aqueous solution of a compound of a metal selected among Ni, Co and Cu is added to the azo compound in an organic solvent.
机译:解决的问题:通过向指定的单偶氮化合物中添加Ni,Co或Cu,以获得耐光性,储存稳定性和耐热性得到改善的金属螯合物。解决方案:将式I表示的氨基化合物(A是与它键合的C和N一起形成噻唑或异恶唑环的残基)重氮化,然后使该产物与式II表示的偶联组分反应( Z 1是可被取代的苯环或可被取代的1-6C烷基或支链烷基; X 1和X 2各自为H,烷基,烷氧基或卤素; E为NY 1 Y 2;且Y 1和Y 2各自为(可以被取代的烷基)得到式III表示的单偶氮化合物。在有机溶剂中将选自Ni,Co和Cu的金属的化合物的甲醇或水溶液添加到偶氮化合物中。

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