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Thin layers of type abo3 with excess - a - type and b - type elements and method for production of integrated circuits with the use of these layers

机译:带有过量a型和b型元素的abo3型薄层以及使用这些薄层的集成电路生产方法

摘要

A method for fabricating an integrated circuit capacitor (10, 20, 30) having a dielectric layer (15, 26, 37) comprising BST with excess A-site and B-site materials such as barium and titanium added. An organometallic or metallic soap precursor solution is prepared (P42) comprising a stock solution of BST of greater than 99.999 % purity blended with excess A-site and B-site materials such as barium and titanium such that the barium is in the range of 0.01-100 mol %, and such that the titanium is in the range of 0.01-100 mol %. A xylene exchange (P44) is then performed to adjust the viscosity of the solution for spin-on application to a substrate. The precursor solution is spun on a first electrode (P45), dried (P46) at 400 DEG C for 2 to 10 minutes, then annealed (P47) at 650 DEG C to 800 DEG C for about an hour to form a layer of BST with excess titanium. A second electrode is deposited (P48), patterned (P49), and annealed at between 650 DEG C to 800 DEG C for about 30 minutes. The resultant capacitor (10, 20, 30) exhibits an enlarged dielectric constant with little change in leakage current.
机译:一种制造具有介电层(15、26、37)的集成电路电容器(10、20、30)的方法,该介电层包括BST,并添加了过量的A位和B位材料,例如钡和钛。制备有机金属或金属皂前体溶液(P42),该溶液包含纯度大于99.999%的BST储备液,并与过量的A位和B位材料(例如钡和钛)混合,使钡的含量在0.01的范围内-100mol%,并且使得钛在0.01-100mol%的范围内。然后进行二甲苯交换(P44)以调节溶液的粘度,以旋涂到基材上。将前体溶液旋转到第一电极(P45)上,在400℃下干燥(P46)2至10分钟,然后在650℃至800℃退火(P47)约一小时,以形成BST层与多余的钛。淀积第二电极(P48),构图(P49),并在650℃至800℃之间退火约30分钟。所得电容器(10、20、30)显示出增大的介电常数,而漏电流几乎没有变化。

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