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New carbene-diene transition metal complex, useful as catalyst in organic reactions, e.g. olefination, contains monodentate imidazoline-type carbene ligand
New carbene-diene transition metal complex, useful as catalyst in organic reactions, e.g. olefination, contains monodentate imidazoline-type carbene ligand
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机译：新的卡宾-二烯过渡金属络合物，可用作有机反应中的催化剂，例如烯化，含有单齿咪唑啉型卡宾配体
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摘要
Carbene-diene complexes (I) of nickel, palladium or platinum are new. Carbene-diene complexes of formula (I) are new. M = nickel, palladium or platinum; L = monodentate carbene ligand of formulae (II) or (III) A, B, C = oxygen, sulfur, CH2, C(R15)a(R16)b, N(R17)c, or Si(R18)d(R19)e; a'' = lone pair of electrons; a-e = 0 or 1 and when at least one is 0, A, B and C may be part of a ring system; x, y, z = 0-1, or a sum of 1-3; R1-R19 = hydrogen, alkyl, aryl, alkenyl, alkoxy, alkylycarbonyloxy, aryloxy, arylcarbonyloxy, fluoro, chloro, hydroxy, nitro, trialkylsilyl, trifluoromethyl, cyano, carboxy, formyl, sulfonic acid, amino (optionally substituted by 1 or 2 alkyl), dialkylphosphinyl, alkyl- or aryl-sulfinyl or -sulfonyl, alkyloxy- or aryloxy-sulfonyl, alkyl-, aryl or alkenyl-thio, alkylcarbonylamino, alkoxycaronyloxy, carbonylamino, alkylcarbonyl, formylamino, alkoxycarbonylamino, arylcarbonyl, aryloxycarbonyl, 2-(alkoxycarbonyl or carboxy)-vinyl, diarylphosphinyl, diaryl- or dialkyl-phosphinyl oxide, phosphonic acid (or its dialkyl ester), or groups of a condensed ring system; all alkyl and alkenyl have 1-10C, optionally branched and/or substituted with chloro, fluoro, alkyl, alkoxy, phenyl, phenoxy, hydroxy, amino or trifluoromethyl; and aryl is 5-10 membered (hetero)aromatic groups, optionally substituted by chloro, fluoro, alkyl, alkoxy, phenyl or phenoxy. An Independent claim is also included for a method for preparing (I).
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机译：镍，钯或铂的碳二烯络合物（I）是新的。式（I）的卡宾-二烯配合物是新的。 M =镍，钯或铂; L =式（II）或（III）的单齿卡宾配体A，B，C =氧，硫，CH2，C（R 15）a（R 16）b，N（R 17）c ，或Si（R 18）d（R 19）e; a''=孤对电子; a-e = 0或1，并且至少一个为0时，A，B和C可能是环系统的一部分; x，y，z = 0-1或1-3之和; R 1 -R 19 ＝氢，烷基，芳基，烯基，烷氧基，烷基羰基氧基，芳氧基，芳基羰基氧基，氟，氯，羟基，硝基，三烷基甲硅烷基，三氟甲基，氰基，羧基，甲酰基，磺酸，氨基（任选被1或2个烷基取代），二烷基亚膦酰基，烷基-或芳基-亚磺酰基或-磺酰基，烷氧基-或芳氧基-磺酰基，烷基-，芳基或烯基-硫基，烷基羰基氨基，烷氧基甲酰氧基，羰基氨基，烷基羰基，甲酰基氨基，烷氧基羰基氨基，芳基羰基，芳氧基羰基，2-（烷氧基羰基或羧基）-乙烯基，二芳基次膦基，二芳基-或二烷基-次膦基氧化物，膦酸（或其二烷基酯）或稠环系统的基团;所有的烷基和烯基具有1-10℃，任选地被氯，氟，烷基，烷氧基，苯基，苯氧基，羟基，氨基或三氟甲基支化和/或取代;芳基是5-10元（杂）芳族基团，任选地被氯，氟，烷基，烷氧基，苯基或苯氧基取代。还包括一种独立的权利要求，涉及一种制备方法（I）。
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