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Process and apparatus for eliminating acid gas using a solvent, for the purification of natural gas

机译:使用溶剂消除酸性气体以纯化天然气的方法和设备

摘要

In the treatment of a gas containing a mixture of hydrocarbons, H2S and possibly CO2, at least part at pressure P2 is put in contact with a recycled polar solvent of which at least 50% is solvent in an adsorption zone (2). The solvent is a non-hydrocarbon organic compound which is normally liquid other than water, at least partially miscible with water and distillable at a temperature below that of water. This produces a purified gas containing most of the hydrocarbons and almost no H2S and a first liquid comprising the solvent, the remaining hydrocarbons and effectively all the H2S and CO2. The solvent is regenerated in at least one distillation column (18), and the regenerated solvent is recycled and refrigerated in the adsorption zone. The first liquid is expanded and heated to a pressure P12 less than P2 in a heat exchange column (12) which exchanges heat in counter-flow with the regenerated and heated solvent. A second gas is recovered at the top of the column, containing effectively all the remaining hydrocarbons and most of the CO2, and at the bottom a second heated liquid is recovered containing the solvent, most of the H2S and a small part of the CO2. The solvent is regenerated by circulating the second liquid, after expansion, through the distillation column at a pressure P18 at most equal to the pressure P12. At least part of a third acid gas is recovered at the top, containing most of the H2S and the remaining CO2, and at the bottom of the column the regenerated and heated solvent is recovered and cooled inside the heat exchange column and the solvent recovered and recycled under pressure in the adsorption zone. Also claimed is a device to carry out the above process.
机译:在处理包含碳氢化合物,H 2 S和可能的CO 2的混合物的气体时,至少一部分压力P2与循环极性溶剂接触,该极性溶剂的至少50%是吸附区(2)中的溶剂。溶剂是非烃有机化合物,其通常是除水以外的液体,至少部分可与水混溶并且可在低于水的温度下蒸馏。这产生了包含大部分烃且几乎不含H2S的纯净气体,以及包含溶剂,剩余烃和有效地包含所有H2S和CO2的第一液体。溶剂在至少一个蒸馏塔(18)中再生,并且再生的溶剂在吸附区中再循环和冷冻。第一液体在热交换塔(12)中膨胀并加热到小于P2的压力P12,该热交换塔与再生和加热的溶剂逆流交换热。在塔顶回收第二种气体,有效地包含所有剩余的烃和大部分CO2,在塔底回收第二种加热的液体,其中包含溶剂,大部分H2S和一小部分CO2。膨胀之后,通过使第二液体在最大等于压力P12的压力P18下循环通过蒸馏塔来再生溶剂。至少一部分第三酸性气体在顶部被回收,其中含有大部分的H2S和剩余的CO2,在塔的底部,被回收和加热的溶剂被回收并在热交换塔内冷却,回收的溶剂在压力下在吸附区循环。还要求保护一种执行上述过程的设备。

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