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Raney nickel catalysts, a method for producing said raney nickel catalysts and the use of the same for hydrogenating organic compounds

机译:阮内镍催化剂,制备所述阮内镍催化剂的方法及其在氢化有机化合物中的用途

摘要

Raney nickel catalysts obtainable by a process in which the melt of an alloy comprising 50 to 94 wt. % aluminum, 10 to 50 wt. % nickel, 0 to 20 wt. % iron, 0 to 15 wt. % cerium, cerium mixed metal, vanadium, niobium, tantalum, chromium, molybdenum or manganese and, optionally, further glass-forming elements is allowed to solidify rapidly with a cooling rate of 104 K/s and the rapidly solidified alloy is then subjected to a treatment with organic or inorganic bases are described.;A process for the preparation of the Raney nickel catalysts mentioned and their use in the hydrogenation of organic compounds, in particular aromatic nitro compounds, are furthermore described.
机译:阮内镍催化剂可通过以下方法获得:其中包含50至94 wt。铝百分比,10至50 wt。镍百分比,0至20 wt。铁百分比,0至15 wt。 %铈,铈混合金属,钒,铌,钽,铬,钼或锰,以及可选地,使其他玻璃形成元素以> 10 4 K / s的冷却速率快速固化还描述了快速固化的合金,然后用有机或无机碱进行了处理。此外,还描述了所述阮内镍催化剂的制备方法及其在有机化合物特别是芳族硝基化合物加氢中的用途。 。

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