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The ionic compound and organic metal or metal compound of the reaction product of compound, no support carbon monoxide-olefin polymeric, catalyst element composition, supported catalyst composition and addition polymerization process
The ionic compound and organic metal or metal compound of the reaction product of compound, no support carbon monoxide-olefin polymeric, catalyst element composition, supported catalyst composition and addition polymerization process
In the present invention, the ionic compound cation and anion for being disclosed a kind of reaction product of compound have at most 100 non-hydrogen atoms, include at least one substituent group comprising active hydrogen partial, thus cation is by following general formula, wherein [Le*-H] e+ Le* represent nitrogen, oxygen, sulphur or phosphorus contain lewis base, including having the alkyl of 10 to 40 carbon atoms from 2 points of 59 minutes C 10-40, there is the carbon atom from 12 to 100 in total, and anion corresponds to general formula [M ' em+Qin (Giq (T H)-natural rubber) iz] ed-, wherein: M is the element of metal or metalloid 5 to 15 periodic table of elements in the periodic table of elements; Q, G represents the description specified in (T-H) of meaning; It is 1 to 7 integer with m; N is integer 0 to 7; Q is integer 0 or 1; R is integer of 1 to 3; Integer z is from I to 8; The integer that d is 1 to 7; With n+z-m value d, correspond to formula M eoRecixXeaiy with above-mentioned organic metal or metal compound, wherein MEO, amusement, the specified meaning of the range of Xea, x and y is as used in the description. The present invention also relates to a kind of catalyst element composition, load and without support carbon monoxide-olefin polymeric, the method containing the compound. These carbon monoxide-olefin polymerics are consequently formed a part of the invention, are also suitable for manufacturing addition polymerization.
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机译：在本发明中，所公开的离子化合物阳离子与阴离子的一种化合物的反应产物具有至多100个非氢原子，包括至少一个包含活性氢部分的取代基，因此阳离子由以下通式表示，其中[Le * -H] e + Le *代表氮，氧，硫或磷所含的路易斯碱，包括从10分钟的2点C 10-40含10至40个碳原子的烷基，有12至20个碳原子总共为100，并且阴离子对应于通式[M'em + Qin（Giq（TH）-天然橡胶）iz] ed-，其中：M为金属或准金属元素周期表中的5至15元素周期表元素表Q，G表示（T-H）中含义的描述; m为1〜7的整数。 N是0至7的整数; Q是整数0或1; R为1〜3的整数。整数z从I到8; d为1到7的整数;具有n + z-m值d，对应于具有上述有机金属或金属化合物的式MeoRecixXeaiy，其中MEO，娱乐性，Xea，x和y的范围的指定含义如描述中所使用。本发明还涉及一种催化剂元素的组成，负载和无载体的一氧化碳-烯烃聚合体，其包含该化合物的方法。这些一氧化碳-烯烃聚合物因此形成本发明的一部分，也适用于制造加成聚合。
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