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PRODUCTION OF BUILT-UP FILM BY LANGMUIR-BLODGETT'S TECHNIQUE COMBINED WITH ELECTROLYTIC OXIDATION POLYMERIZATION

机译:朗缪尔-布洛吉特技术与电解氧化聚合相结合生产增强膜

摘要

PURPOSE:To obtain a built-up film having superior functional properties by the Langmuir-Blodgett's(LB) technique without using aniline having a higher alkyl group by subjecting monomers selected among alkyl substd. anilines to electrolytic oxidation polymn. with an electrically conductive substrate as a working electrode. CONSTITUTION:One or more kinds of monomers selected among alkyl substd. anilines are used. An acidic aq. soln. and an electrolyte are put in a trough and the monomers are dissolved in a uonpolar org. solvent and poured in the trough. A substrate is continuously and vertically moved between the inside and outside of the trough while impressing constant electric potential on the substrate. By this operation, a film of the monomers is formed by the LB technique, electrolytic oxidation polymn. proceeds during film formation and a built-up film of a polymer is formed.
机译:目的:通过使选自烷基的单体通过Langmuir-Blodgett(LB)技术获得具有优异功能特性的组合膜而无需使用具有更高烷基的苯胺。苯胺电解氧化聚乙烯。带有导电基板作为工作电极。组成:一种或多种选自烷基的单体。使用苯胺。酸性水溶液soln。将电解质放入槽中,并将单体溶解在非极性有机溶剂中。溶剂,倒入槽中。基板在槽的内部和外部之间连续垂直移动,同时在基板上施加恒定的电势。通过该操作,通过LB技术(电解氧化聚合物)形成单体的膜。在成膜过程中进行,形成聚合物的堆积膜。

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