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PROCESS FOR PRODUCING Bi-Ca-Sr-Cu-O, Tl-Ca-Sr-Cu-O AND Tl-Ba-Ca-Cu-O SUPERCONDUCTING CERAMICS

机译:生产Bi-Ca-Sr-Cu-O,Tl-Ca-Sr-Cu-O和Tl-Ba-Ca-Cu-O超导陶瓷的过程

摘要

A process for producing superconducting (Bi. T1 )-Ca-(Sr, Ba)-Cu-O ceramic suffering less variation in components, which comprises mixing a calcium compound, a strontium or barium compound and a copper oxide, each of which has a low vapor pressure among the powdery starting materials, in predetermined proportions, subjecting the mixture to primary firing at a predetermined temperature of 850 to |050°C to form a Ca-(Sr, Ba)-Cu-O oxide, mixing this oxide with a bismuth or thallium oxide, each of which has a high vapor pressure among the starting materials, and subjecting the mixture to secondary firing at a predetermined temperature of 500 to 820°C.
机译:一种成分变化较小的超导(Bi.T1)-Ca-(Sr,Ba)-Cu-O陶瓷的制备方法,该方法包括将钙化合物,锶或钡化合物和氧化铜混合,每种均具有在粉末状原料中以预定比例的低蒸气压,使混合物在850至| 050°C的预定温度下初烧,形成Ca-(Sr,Ba)-Cu-O氧化物,并将其混合用氧化铋或氧化,,在原料中具有高蒸气压的<!-EPO ->的每一种,并在预定温度500至250℃下对混合物进行二次焙烧。 820℃。

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