首页> 外国专利> procedures for the extraction of o - chlornitrobenzol from a mixture of chlornitrobenzol o -, m chlornitrobenzol and / or p - chlornitrobenzol

procedures for the extraction of o - chlornitrobenzol from a mixture of chlornitrobenzol o -, m chlornitrobenzol and / or p - chlornitrobenzol

机译:从邻硝基氯邻硝基邻硝基邻硝基邻氯硝基苯对氯硝基苯的混合物中提取邻氯硝基苯的方法

摘要

An adsorptive separation process for separating ortho- chloronitrobenzene from a feed mixture comprising ortho- chloronitrobenzene and at least one other isomer of chloronitrobenzene, which process comprises contacting the feed mixture with an adsorbent comprising a type X or type Y zeolite containing at the exchangeable cationic sites one or more cations selected from the group consisting of Groups IA, IIA and the transition metals of the Periodic Table of Elements, selectively adsorbing substantially all of the said ortho- chloronitrobenzene to the substantial exclusion of the remaining isomers and thereafter recovering high-purity ortho-chloronitrobenzene. A desorption step may be used to desorb the adsorbed ortho- chloronitrobenzene.
机译:从包含邻氯硝基苯和氯硝基苯的至少一种其他异构体的进料混合物中分离邻氯硝基苯的吸附分离方法,该方法包括使进料混合物与包含X型或Y型沸石的吸附剂接触,该吸附剂包含在可交换的阳离子位点选自IA,IIA族和元素周期表的过渡金属的一种或多种阳离子,选择性地吸附基本上所有的所述邻氯硝基苯,基本上排除了其余的异构体,然后回收了高纯度的邻位-氯硝基苯。可以使用解吸步骤来解吸吸附的邻氯硝基苯。

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