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Lignin and cellulose recovery from hardwoods - by alkaline acid digestion, organic solvent extn., concn and alkali chlorite and hydroxide treatment

机译:从硬木中回收木质素和纤维素-通过碱酸消化,有机溶剂萃取,浓缩和碱式亚氯酸盐和氢氧化物处理

摘要

Lignin and cellulose are recovered from hardwood, e.g. beech and birch, by (a) organic solvent extn. of the solid residue obtd. by digesting hardwood in 2 steps: (1) with a 4(0.5-2) wt % concn. alkali hydroxide soln. and (2) with inorganic acid, and concentrating the organic soln. to recover lignin, and (b) recovering cellulose by treating residue from step (a) with alkali chlorite soln. and then (c) treating with alkali hydroxide soln. at raised temp. The reactive non-polymerised, thermoplastic lignin obtd. can be used as raw matl. for dyes and pesticides. Cellulose obtd. is white. The process allows the complete utilisation of the starting matl.
机译:木质素和纤维素是从硬木中回收的,例如山毛榉和桦木,通过(a)有机溶剂提取。残留的固体残渣。通过2个步骤消化硬木:(1)的浓度为4(0.5-2)wt%。碱金属氢氧化物溶液。 (2)用无机酸浓缩有机溶液。回收木质素,以及(b)通过用碱亚氯酸盐溶液处理步骤(a)中的残留物来回收纤维素。然后(c)用碱金属氢氧化物溶液处理。在升高的温度下活性非聚合热塑性热塑性木质素。可用作原料。用于染料和农药。纤维素。是白色的。该过程允许完全利用起始物质。

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