首页> 外国专利> MESOPOREOUS AND MACROPOROUS NICKEL BASED CATALYST WITH A MEDIAN MACROPOROUS DIAMETER BETWEEN 50 NM AND 200 NM AND ITS USE IN HYDROGENATION

MESOPOREOUS AND MACROPOROUS NICKEL BASED CATALYST WITH A MEDIAN MACROPOROUS DIAMETER BETWEEN 50 NM AND 200 NM AND ITS USE IN HYDROGENATION

机译:基于中间渗透性和大孔镍的催化剂,中值大孔直径在50nm和200nm之间,其用于氢化

摘要

The invention relates to a supported catalyst comprising a predominantly calcined aluminum oxide support and an active phase comprising nickel, the nickel content being between 5 and 65% by weight of said element relative to the total mass of the catalyst, said active phase not comprising no group VIB metal, nickel particles having a diameter less than or equal to 20 nm, said catalyst having a mesoporous median diameter between 14 nm and 30 nm, a macroporous median diameter between 50 and 200 nm, a mesoporous volume measured by mercury porosimetry greater than or equal to 0.40 mL / g and a total pore volume measured by mercury porosimetry greater than or equal to 0.42 mL / g. The invention also relates to the process for preparing said catalyst and its use in a hydrogenation process.
机译:本发明涉及包含主要煅烧的氧化铝载体和包含镍的活性相的负载型催化剂,所述镍含量相对于催化剂的总质量为5至65%重量的所述元件,所述活性阶段不包含NO组VIB金属,直径小于或等于20nm的镍颗粒,所述催化剂在14nm和30nm之间的介孔中值直径,大孔中值直径在50至200nm之间,由汞孔隙测量的介孔体积大于或等于0.40ml / g,通过汞孔隙率测量的总孔体积大于或等于0.42ml / g。本发明还涉及制备所述催化剂的方法及其在氢化过程中的用途。

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