surfactant

摘要： Environment friendly and intelligent surfactants have attracted great attention in recent years.A bio-based CO_(2)responsive surfactant rosin acid dimaleimide choline(R-BMI-C)with an extremely rigid skeleton was prepared using rosin and choline as raw materials by Diels-Alder addition reaction and acid-base neutralization reactions.Its structure was confirmed by IR and^(1)H NMR spectra.The foams’properties of R-BMI-C could be adjusted by bubbling CO_(2)/N_(2)to change the structure of the surfactant.At pH 10.4,R-BMI-C forms an unstable foam with a half-life of 1.5 h.When the pH was reduced to 7.4 by bubbling CO_(2),R-BMI-C forms an extremely stable foam with a half-life of 336 h.The surfactant R-BMI-C changed from bola type to conventional type when bubbling CO_(2).And the internal aggregation structure of R-BMI-C aqueous solution changed from spherical micelles to laminar micelles according to the cryogenic-transmission electron microscope.We know that the lamellar structure tends to adsorb at the air/water interface or is trapped in the foam film,which slows down the foam coarsening and agglomeration process,resulting in a significant increase in foam stability.R-BMI-C could be used in oil extraction,fire-fighting and chemical decontamination due to its excellent foaming,stabilization and defoaming properties.

摘要： In the process of water-flooding development of heavy oil reservoir,due to the high viscosity and oil-water mobility ratio of heavy oil,there are some problems such as poor fluidity,high residual oil saturation and low recovery efficiency,which seriously restrict the efficient development of heavy oil.The molecular structure characteristics of asphaltenes and resins in heavy oil were analyzed.Based on the three most concerned properties of chemical agents,including the emulsification performance,the interface performance and the oil washing performance,three chemical oil displacement agents for heavy oil reservoirs were developed,and the structure of the chemical agents were characterized by high resolution mass spectrometry.The performance evaluation of chemical agents and core displacement experiments show that there is no obvious correlation between the properties of chemical agents,including interfacial tension,emulsifying ability and oil washing ability.For heavy oil reservoirs,the emulsification and viscosity reduction performance of chemical agents was more important than the oil washing capacity,and the oil washing capacity was more important than the interface performance.Viscosity reduction performance was the key parameter of oil displacement agent suitable for heavy oil reservoir.The composite binary system consisting of the viscosity reducer and the polymer had better oil recovery than using viscosity reducer alone.

摘要： The existing researches on surfactant micellar solutions mainly focus on the formulation optimization and core flooding test, and the types and mechanisms of cleanup additives suitable for low permeability reservoir remain unclear. The flowback efficiencies of different types of surfactant micellar solutions were evaluated by core experiments, a multi-level pore-throat system micromodel characterizing pore-throat structures of low permeability reservoir was made, and flooding and flowback experiments of brine and surfactant micellar solutions of different salinities were conducted with the micromodel to show the oil flowback process in micron pores under the effect of surfactant micellar solution visually and reveal the mechanisms of enhancing displacement and flowback efficiency of surfactant micellar solution. During the displacement and flowback of brine and low salinity surfactant micellar solution, many small droplets were produced, when the small droplets passed through pore-throats, huge percolation resistance was created due to Jamin’s effect, leading to the rise of displacement and flowback pressure differences and the drop of flowback efficiency. The surfactant micellar solutions with critical salinity and optimal salinity that were miscible with crude oil to form Winsor Ⅲ micro-emulsion didnot produce mass small droplets, so they could effectively reduce percolation resistance and enhance oil displacement and flowback efficiency.

摘要： Measure the chemiluminescence value of acridine compound as luminescent agent in the surfactant solution with a series of concentrations,according to the value of the obtained luminescent value and the value of the corresponding surfactant concentration in the surfactant solution,linear fitting is carried out to obtain several fitting lines,and the minimum value of the surfactant concentration corresponding to the intersection of the two adjacent fitting lines is the critical micelle concentration of the surfactant.According to the results,the critical micelle concentration of Dodecyl trimethyl ammonium chloride is 11.5 mmol/L,Hexadecyl trimethyl ammonium Bromide is 0.357 mmol/L,Sodium dodecyl sulfate is 7.64 mmol/L,sodium N-lauroylsarcosinate is 0.890 mmol/L,Triton X-100 is 0.309 mmol/L,3-((3-Cholamidopropyl)dimethylammonium)-1-propanesulfonate is 9.53 mmol/L,3-(N,N-dimethyldodecylammonio)propanesulfonate is 1.73 mmol/L.The results were similar to those obtained by traditional methods,the method can be used in the study of critical micelle concentration of surfactants.

摘要： Surfactants are the most essential active substances in detergents,and their standardization process has a significant impact on the development of the surfactant industry.The development history of the standardization of detergents has been introduced previously.Herein,from the perspective of standardization,the development history of various surfactant products has been reviewed and analyzed in detail.Moreover,the development history of the main raw materials for surfactant synthesis has also been introduced briefly.

摘要： Sorted out the legal system of cosmetics registration and filing,mainly adopted on the Regulations on the Supervision and Administration of Cosmetics,Administrative Measures for Registration and Filing of Cosmetics,Regulations on the Administration of Cosmetics Registration and Filing Documents,analyzed and summarized the relevant laws and regulations related to the management of cosmetics label,and discussed the background and significance of Measures for the Management of Cosmetics Label in detail.On the basis of summarizing and analyzing the problems and current situation faced by the current label management,this paper put forward reasonable suggestions to the filer and regulatory authorities,so as to provide certain guiding significance for the declaration and evaluation of ordinary cosmetics labels.

摘要： A Simple,Rapid,Comparative Evaluation of Multiple Products for Decontamination of Actinidecontaminated Rat Skin Ex Vivo Nina M.Griffiths1,Karine Devilliers1,Pierre Laroche2,Anne Van der Meeren1(1.Laboratory of RadioToxicology,CEA,Paris-Saclay University,Bruyères le Chatel,France;2.Direction of Health,Security,Environment&Radioprotection,ORANO,Paris,France)Abstract:Decontamination of skin is an important medical countermeasure in order to limit potential internal contamination by radionuclides such as actinides.Minimizing skin surface contamination will ultimately prevent internal contamination and subsequent committed effective dose as well as contamination spreading.The decontamination agents tested on a rat skin ex vivo model ranged from water to hydrogel wound dressings.A surfactant-containing cleansing gel and calixarene nanoemulsion with chelation properties demonstrated marked decontamination efficacies as compared with water or the chelator DTPA.

摘要： The organic compounds contaminated soil substantially threatens the growth of plants and food safety.In this study,we synthesis zero-valent bimetallic Fe/Cu catalysts for the degradation of 2,4-dichlorophenol(DCP)in soils with persulfate(PS)in combination of organic surfactants and exploring the main environmental impact factors.The kinetic experiments show that the 5%(mass)dosage of Fe/Cu exhibits a higher degradation efficiency(86%)of DCP in soils,and the degradation efficiency of DCP increases with the increase of the initial PS concentration.Acidic conditions are favorable for the DCP degradation in soils.More importantly,the addition of Tween-80,and Triton-100 can obviously desorb DCP from the soil surface,which enhances the degradation efficiency of DCP in soils by Fe/Cu and PS reaction system.Furthermore,the Quenching experiments demonstrate that SO_(4)^(-1)·and·OH are the predominant radicals for the degradation of DCP during the Fe/Cu and PS reaction system as well as non-radical also exist.The findings of this work provide an effective method for remediating DCP from soils.

摘要： Prolonged exposure to coal dust leads to various lung disorders, including incurable coal workers’ pneumoconiosis (CWP), and endangers miners’ health in underground mines. This article summarizes the latest research progress in dust control technology, including chemical dust suppressants, foam dust removal, ultrasonic atomization, magnetized water dust suppression, double curtains of wind and fog, biological nano-film, and emerging microbial dust suppressants in the field of dust. The actual application compares and analyzes the advantages and disadvantages of different dust removal technologies. The current three directions of mine dust prevention and control are pointed out: the prevention and control of respirable dust, hydrophobic dust, and secondary dust, and the prospects for future development trends. Given the treatment of respirable dust, it is necessary to strengthen the research on the dust generation mechanism under different working conditions and to explore the migration and settlement laws of respirable dust by constructing a numerical model of dust dynamics;for the treatment of hydrophobic dust, further research on the microphysical and chemical properties of coal dust is needed. The relationship between wettability and continuously optimizing the wetting agent;for the prevention and control of secondary dust in coal mines, emerging microbial dust suppression technologies need to be developed to explore the micro-action between microorganisms and coal dust molecules to achieve green prevention and control of dust.

摘要： Chemical loss such as surfactants and alkalis by adsorption to reservoir rock surface is an important issue in enhanced oil recovery(EOR). Here, we investigated the adsorption behaviors of anionic surfactants and alkalis on silica for the first time as a function of temperature using quartz crystal microbalance with dissipation(QCM-D). The results demonstrated that the temperature dependent critical micelle concentration of alcohol alkoxy sulfate(AAS) surfactant can be quantitatively described by the thermodynamics parameters of micellization, showing a mainly entropy-driven process. AAS adsorption was mediated under varying temperature conditions, by divalent cations for bridging effect, monovalent cations competitive for adsorption sites but not giving cation bridging, pH regulation of deprotonated sites of silica, presence of alkoxy groups in the surfactants, and synergistic effect of surfactant coinjection. The addition of organic alkalis can enhance the overall adsorption of the species with AAS,whereas inorganic alkali of Na_(2) CO_3 had capability of the sequestration of the divalent ions, whose addition would reduce AAS adsorption. The typical AAS adsorption indicated a non-rigid multilayer,estimated to have between 2 and 5 layers, with a likely compact bilayer followed by disorganized and unstable further layering. The new fundamental understanding about temperature effect on surfactants and alkalis adsorption contributes to optimizing the flooding conditions of chemicals and developing more efficient mitigation strategies.

摘要： 一种利用oil‑in‑surfactant制备的超白纳米乳液，其配方重量配比如下：纯化水：20％‑40％，多元醇：10％‑30％，乳化剂：4％‑10％，油脂：30％‑60％；油脂折光率比普通油脂的折光率高，所以制备出来的纳米乳液的白度比其他乳液更高。将其制备出来的高白度的纳米乳液稀释，只要稍加悬浮稳定剂就能制备出超高白度并且低粘度的化妆水，面膜精华液等。解决了低粘度乳化液的稳定性。而由于粒径比普通乳液小，所以吸收性会比普通乳液更强，肤感较普通乳液更加清爽，适合各类皮肤。