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To Explore High Magnetoelectrochemical Chirality

机译:探索高磁电化学手性

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摘要

Cu films were electrodeposited under a magnetic field of 5 T on the Pt disc electrodes with diameters of 3 mm~25 μm.Such magnetoelectrodeposited(MED)Cu films were employed as an electrode,and cyclic voltammograms were measured for the electrochemical reactions of an amino acid of alanine.Chiral behavior was observed as oxidation current difference between the enantiomers.Clear magnetoelectrochemical chirality was observed on the micro-disk electrode and on the kinetic-controlled electrode process of alanine.The chiral response was durable for more than 10 cycles of the consecutive voltammetric measurements of the enantiomers.
机译:在5 T的磁场下,在直径3 mm〜25μm的Pt圆盘电极上电沉积Cu膜。以此类磁电沉积(MED)Cu膜为电极,并通过循环伏安图测量氨基的电化学反应。观察到手性行为是对映异构体之间的氧化电流差;在微盘电极和动力学控制的丙氨酸电极上观察到清晰的磁电化学手性;手性反应在超过10个循环的周期内持久对映体的连续伏安测量。

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