Thermal and optical study of the new methacrylic copolymers useful in POF technology

机译：用于POF技术的新型甲基丙烯酸共聚物的热学和光学研究

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This study the copolymerization and physico-chemical properties of the new copolymers of meth/acrylic esters: butyl acrylate (AB), ethylhexyl acrylate (AEH), or methyl methacrylate (MMA) with 2,2,2-trifluoroethyl methacrylate (TFEMA) used as a dopant are presented. Chemical structures of the copolymers were confirmed by attenuated total reflection-Fourier transform infrared (ATR/FT-IR) spectroscopy. Thermal properties of the synthesized materials were investigated by means DSC (Differential Scanning Calorimetry) and TG/DTG analyses. The influence of fluorinated dopant on the thermal and optical properties of the copolymers were evaluated in detail.

机译：这项研究研究了以下新的甲基/丙烯酸酯共聚物的共聚和理化性质：丙烯酸丁酯（AB），丙烯酸乙基己酯（AEH）或甲基丙烯酸甲酯（MMA）与2,2,2-三氟甲基丙烯酸乙酯（TFEMA）作为掺杂剂。通过衰减全反射-傅立叶变换红外光谱（ATR / FT-IR）光谱确认了共聚物的化学结构。通过DSC（差示扫描量热法）和TG / DTG分析研究了合成材料的热性能。详细评估了氟化掺杂剂对共聚物的热和光学性能的影响。

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来源
《13th Conference on Integrated Optics: Sensors, Sensing Structures, and Methods》|2018年|1083009.1-1083009.8|共8页
会议地点 Szczyrk(PL)
作者
B. Podkoscielna; K. Fila; M. Goliszek; M. Gargol; B. Gawdzik; M. Gil; P. Mergo;
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作者单位

Department of Polymer Chemistry, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Department of Polymer Chemistry, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Department of Polymer Chemistry, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Department of Polymer Chemistry, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Department of Polymer Chemistry, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Laboratory of Optical Fibre Technology Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

Laboratory of Optical Fibre Technology Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland;

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正文语种 eng
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关键词
meth/acrylic copolymers; synthesis; 2,2,2-trifluoroethyl methacrylate; ATR/FTIR; thermogravimetric analysis; thermal properties; DSC; optical properties;

机译：甲基/丙烯酸共聚物；合成;甲基丙烯酸2,2,2-三氟乙酯; ATR / FTIR；热重分析；热性能; DSC；光学性质;

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1. Structural, thermal and optical properties of Cu$^{2+}$ doped methacrylic acid–ethyl acrylate (MAA:EA) copolymer films [J] . Y MADHAVA KUMAR, N O GOPAL, Ch RAMU, Bulletin of materials science . 2017,第5期

机译：Cu $ ^ {2 +} $掺杂的甲基丙烯酸-丙烯酸乙酯（MAA：EA）共聚物薄膜的结构，热和光学性质
2. Structural, thermal and optical properties of Cu2+ doped methacrylic acid-ethyl acrylate (MAA:EA) copolymer films [J] . Kumar Y. Madhava, Gopal N. O., Ramu Ch, Bulletin of Materials Science . 2017,第5期

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3. Relevant chiroptical and thermal properties in optically active methacrylic copolymers containing carbazole and azoaromatic chromophores in the side-chain [J] . Luigi Angiolini, Tiziana Benelli, Loris Giorgini, Reactive & Functional Polymers . 2009,第12期

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4. Thermal and optical study of the new methacrylic copolymers useful in POF technology [C] . B. Podkoscielna, K. Fila, M. Goliszek, Conference on Integrated Optics: Sensors, Sensing Structures, and Methods . 2018

机译：用于POF技术的新型甲基丙烯酸共聚物的热敏和光学研究
5. Thermal Analysis, Structural Studies and Morphology of Spider Silk-like Block Copolymers. [D] . Huang, Wenwen. 2013

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6. Thermal characteristics of the self-healing response in poly(ethylene-co-methacrylic acid) copolymers [O] . Stephen J Kalista Jr, Thomas C Ward 2007

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8. Water-Soluble Copolymers. 53. (23)Na NMR Studies of Hydrophobically-ModifiedPolyacids: Copolymers of 2-(1-Naphthylacetamido) ethylacrylamide with Acrylic Acid and Methacrylic Acid [R] . Newman, J. K., McCormick, C. L. 1994

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Thermal and optical study of the new methacrylic copolymers useful in POF technology

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