New approach to the theory of additives solubility in polymers

机译：添加剂在聚合物中溶解度理论的新方法

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Additives and gases during dissolution in the polymer occupy zones with lower density packing which are the elements of disorder in the arrangement of macromolecules either of relaxation or of topological nature. If the free volume is less than that necessary for sopriton of the additive molecule, the dissolution requires rearrangement of this center resulting in change of the polymer structure. This could be particularly important for large sized molecules. The regularities in the solubility, migration and chemical reactions of additives in polymers in the light of their non-unique distribution are discussed.

机译：在聚合物中溶解期间的添加剂和气体占据较低密度堆积的区域，这些区域是松弛或具有拓扑性质的大分子排列中的无序元素。如果自由体积小于添加剂分子悬浮液所需的自由体积，则溶解需要重新排列该中心，从而导致聚合物结构改变。这对于大分子而言可能尤其重要。根据添加剂的非唯一分布，讨论了添加剂在聚合物中的溶解度，迁移和化学反应的规律。

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《The Eighth International Conference on Additives '99 March 22-24, 1999 San Francisco, California》|1999年|p.1-11|共11页
会议地点 San Francisco CA(US)
作者
Alexander Marin;
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正文语种 eng
中图分类化学工业;
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New approach to the theory of additives solubility in polymers

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