ELECTRON TRANSFER TO ENDOPEROXIDES: 3,3,6,6-TETRAARYL-1,2-DIOXANES AS MECHANSITIC PROBES

机译：电子向内毒素的转移：3,3,6,6-四芳基-1,2-二恶烷作为机电探针

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The electron transfer (ET) reduction of 3,3,6,6-tetraphenyl-1,2-dioxane (TPD) was studied to determine the influence of the aryl moiety on the ET reactivity of endoperoxides. It was determined that the initial ET occurs via competitive concerted and stepwise dissociative processes that result in the cleavage of the O-O bond. The distonic radical anion intermediate generated from the initial ET was found to have competing modes of reactivity, either a second ET or fragmentation process. The latter leads to the formation of the benzophenone radical anion that is the propagating species in an uncommon ET chain mechanism. The pathway followed by the distonic radical anion intermediate was dependent on whether the electron donor was heterogeneous (an electrode) or homogeneous (a radical anion in solution) and the driving force.

机译：研究了3,3,6,6-四苯基-1,2-二恶烷（TPD）的电子转移（ET）还原，以确定芳基部分对内过氧化物的ET反应性的影响。已确定初始ET是通过竞争性协调一致的逐步解离过程发生的，该过程导致O-O键断裂。发现从初始ET产生的二元自由基阴离子中间体具有竞争性的反应模式，无论是第二个ET还是裂解过程。后者导致二苯甲酮自由基阴离子的形成，这是一种不常见的ET链机理中的繁殖物种。二烯基自由基阴离子中间体所遵循的途径取决于电子给体是异质的（电极）还是均质的（溶液中的自由基阴离子）和驱动力。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.89-92|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Donald L. B. Stringle; Mark S. Workentin;
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Department of Chemistry, University of Western Ontario London, ON, Canada N6A 5B7;

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原文格式 PDF
正文语种 eng
中图分类化学;
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1. Efficient Homogeneous Radical-Anion Chain Reactions Initiated by Dissociative Electron Transfer to 3,3,6,6-Tetraaryl-1,2-dioxanes [J] . Donald L. B. Stringle, David C. Magri, Mark S. Workentin Chemistry: A European journal . 2010,第1期

机译：通过解离电子转移到3,3,6,6-Tetraaryl-1,2-dioxanes的有效均相自由基阴离子链反应
2. Efficient Homogeneous Radical-Anion Chain Reactions Initiated by Dissociative Electron Transfer to 3,3,6,6-Tetraaryl-1,2-dioxanes [J] . Donald L. B. Stringle Dr., David C. Magri Dr., Mark S. Workentin Prof. Chemistry - A European Journal . 2010,第1期

机译：通过解离电子转移到3,3,6,6-Tetraaryl-1,2-dioxanes的有效均相自由基阴离子链反应
3. Synthesis of 3,3,6,6-Tetraaryl-l,2-Dioxanes via TiO_2-catalyzed Photooxygenation of 1,1-Diarylethenes in the Presence of Mg(ClO_4)_2 [J] . Hajime Maeda, Hisayuki Miyamoto, Kazuhiko Mizuno Chemistry Letters . 2004,第4期

机译：Mg（ClO_4）_2存在下TiO_2催化1,1-二芳烃的光氧合反应合成3,3,6,6-四芳基-1,2-二恶烷
4. Electron transfer to endoperoxides: 3,3,6,6-tetraaryl-1,2-dioxanes as mechansitic probes [C] . Donald L. B. Stringle, Mark S. Workentin International Manuel M. Baizer Symposium . 2002

机译：电子转移到内透铁氧化物：3,3,6,6-四芳基-1,2-二氧烷作为Mechansitic探针
5. Electron transfer reduction of biologically relevant endoperoxides. [D] . Donkers, Robert L. 2001

机译：生物相关的内过氧化物的电子转移还原。
6. Dissociative Electron Transfer to Diphenyl-Substituted Bicyclic Endoperoxides: The Effect of Molecular Structure on the Reactivity of Distonic Radical Anions and Determination of Thermochemical Parameters [O] . David C. Magri, Mark S. Workentin 2014

机译：解离电子转移到二苯基取代的双环内过氧化物：分子结构对张力自由基阴离子反应性的影响和热化学参数的确定
7. Dissociative Electron Transfer to Diphenyl-Substituted Bicyclic Endoperoxides: The Effect of Molecular Structure on the Reactivity of Distonic Radical Anions and Determination of Thermochemical Parameters [O] . David C. Magri, Mark S. Workentin 2014

机译：离解电子转移到二苯基取代的双环内过氧化物：分子结构对Distonic自由基阴离子反应性的影响及热化学参数的测定
8. Health Advisories for 25 Organics (Including Acrylamide, Benzene, Carbon Tetrachloride, Chlorobenzene, Dichlorobenzene(s), 1,2-Dichloroethane, 1,1-Dichloroethylene, Cis-1,2-Dichloroethylene, Trans-1,2-Dichloroethylene, Dichloromethane, P-Dioxane, Dioxin, Epichlorohydrin, Ethylbeneze, Ethylene Glycol, Hexachlorobenezene, Hexane, Methyl Ethyl Ketone, Styrene, Tetrachloroethylene, Toluene, 1,1,1-Trichloroethane, Trichloroethylene, Vinyl Chloride, Xylenes) (RE-ANNOUNCEMENT of PB87-206306 - see notes field for explanation) [R] . 1987

机译：25种有机物的健康咨询（包括丙烯酰胺，苯，四氯化碳，氯苯，二氯苯，1,2-二氯乙烷，1,1-二氯乙烯，顺-1,2-二氯乙烯，反式-1,2-二氯乙烯，二氯甲烷），对二恶烷，二恶英，环氧氯丙烷，乙基苯乙烯，乙二醇，六氯苯，己烷，甲基乙基酮，苯乙烯，四氯乙烯，甲苯，1,1,1-三氯乙烷，三氯乙烯，氯乙烯，二甲苯）（pB87-的重新公告） 206306 - 请参阅备注字段以获取解释）

ELECTRON TRANSFER TO ENDOPEROXIDES: 3,3,6,6-TETRAARYL-1,2-DIOXANES AS MECHANSITIC PROBES

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