STRUCTURE OF SILICA GELS MADE FROM TETRAETHOXYSILANE AND TRIETHOXYSILANE BY NOVEL SOL-GEL METHOD

机译：新型溶胶-凝胶法由四乙氧基硅烷和三乙氧基硅烷制成的硅胶结构

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Silica gels were made from tetraethoxysilane and triethoxysilane by the novel sol-gel process in which oligomeric cyclic siloxane preferably produced in the early stage of hydrolysis reaction were subjected to ring-opening polymerization catalyzed by NaOH. Their structure was examined by IR spectroscopy and X-ray radial distribution analysis method. It was found that the silica gels made by such a novel sol-gel process had the medium-range-structure very similar to silica glass. In other words, 6-fold siloxane ring structure unit was prevailing in the novel gels, while silica gels prepared via conventional sol-gel route were constructed with 4-fold siloxane rings.

机译：通过新颖的溶胶-凝胶法，由四乙氧基硅烷和三乙氧基硅烷制备硅胶，其中优选将在水解反应的早期阶段产生的低聚环状硅氧烷进行NaOH催化的开环聚合。通过红外光谱和X射线径向分布分析方法检查了它们的结构。发现通过这种新颖的溶胶-凝胶法制备的硅胶具有与硅胶玻璃非常相似的中等范围结构。换句话说，新型凝胶中普遍使用6倍硅氧烷环结构单元，而用4倍硅氧烷环构造通过常规溶胶-凝胶路线制备的硅胶。

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《Formation, structure and properties of glasses》|1994年|145-152|共8页
会议地点 Beijing(CN)
作者
Kanichi KAMIYA; Masao IZUMI; Tomonori DOKAI; Jun MATSUOKA; Hiroyuki NASU;
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Department of Chemistry for Materials, Faculty of Engineering, Mie University Kamihama-cho, Tsu-shi, Mie-ken 514, Japan;

Department of Chemistry for Materials, Faculty of Engineering, Mie University Kamihama-cho, Tsu-shi, Mie-ken 514, Japan;

Department of Chemistry for Materials, Faculty of Engineering, Mie University Kamihama-cho, Tsu-shi, Mie-ken 514, Japan;

Department of Chemistry for Materials, Faculty of Engineering, Mie University Kamihama-cho, Tsu-shi, Mie-ken 514, Japan;

Department of Chemistry for Materials, Faculty of Engineering, Mie University Kamihama-cho, Tsu-shi, Mie-ken 514, Japan;

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正文语种 eng
中图分类玻璃工业;
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1. Study of Sol-gel reaction of organically modified alkoxysilanes. Part I: Investigation of hydrolysis and polycondensation of phenylaminomethyl triethoxysilane and tetraethoxysilane [J] . Wu CM, Wu YH, Xu TW, Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2006,第52a54期

机译：有机改性烷氧基硅烷的溶胶-凝胶反应研究。第一部分：苯氨基甲基三乙氧基硅烷和四乙氧基硅烷的水解和缩聚研究
2. Sol-Gel Synthesis and Microstructure Analysis of Amino-Modified Hybrid Silica Nanoparticles from Aminopropyltriethoxysilane and Tetraethoxysilane [J] . Song Chen, Satoshi Hayakawa, Yuki Shirosaki, Journal of the American Ceramic Society . 2009,第9期

机译：氨基丙基三乙氧基硅烷和四乙氧基硅烷对氨基改性杂化二氧化硅纳米粒子的溶胶-凝胶合成及微观结构分析
3. Biohybrid of methylotrophic yeast and organically modified silica gels from sol-gel chemistry of tetraethoxysilane and dimethyldiethoxysilane [J] . Ponamoreva O. N., Lavrova D. G., Kamanina O. A., Journal of Sol-Gel Science and Technology . 2019,第2期

机译：来自四乙氧基硅烷和二甲基二乙醇硅烷的溶胶 - 凝胶化学的甲基嗜型酵母和有机改性硅胶的生物凋亡
4. STRUCTURE OF SILICA GELS MADE FROM TETRAETHOXYSILANE AND TRIETHOXYSILANE BY NOVEL SOL-GEL METHOD [C] . China-Japan-Russia trilateral seminar on glassess . 1994

机译：通过新型溶胶 - 凝胶法由四乙氧基硅烷和三乙氧基硅烷制成的硅胶的结构
5. Phenyl Functionalized Sol-gel Silica Sorbent for Capillary Microextraction and Chromia-Based Sol-gel Ucon Stationary Phase for Capillary Gas Chromatography. [D] . McLean, Michael M. 2014

机译：用于毛细管微萃取的苯基官能化溶胶-凝胶硅胶吸附剂和用于毛细管气相色谱的基于铬的溶胶-凝胶Ucon固定相。
6. The synthesis of controlled shape nanoplasmonic silver-silica structures by combining sol-gel technique and direct silver reduction [O] . Lina Ramanauskaite, Valentinas Snitka 2015

机译：溶胶-凝胶技术与直接银还原相结合合成可控形状的纳米等离子体银-二氧化硅结构
7. Raman Spectra of Silica Gel Prepared from Triethoxysilane and Tetraethoxysilane by the Sol-Gel Method [O] . Kazunori MATSUI, Hisao SATOH, Michihisa KYOTO 1998

机译：通过溶胶 - 凝胶法制备二乙氧基硅烷和四乙氧基硅烷制备硅胶的拉曼光谱
8. Multinuclear NMR Study of Aluminosilicate Sol-Gel Synthesis Reasons for theHomogeneous Gelation Using the Prehydrolysis Method [R] . Pozarnsky, G. A., McCormick, A. V. 1993

机译：硅酸盐溶胶 - 凝胶合成的多核核磁共振研究使用预水解法进行均相凝胶化的原因

STRUCTURE OF SILICA GELS MADE FROM TETRAETHOXYSILANE AND TRIETHOXYSILANE BY NOVEL SOL-GEL METHOD

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