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Fixation and conversion of CO_2 using ionic liquids

机译:使用离子液体固定和转化CO_2

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摘要

Ionic liquids (ILs), a kind of novel green media composed entirely of cations and anions, have recently attracted considerable attention due to their unique properties such as non-volatility, tunable polarity, high stability and so on. In this work, the latest progress on the fixation and conversion of carbon dioxide (CO_2) using ILs as absorbents, catalysts or promoters has been summarized. The absorption performance of conventional ILs and task-specific ILs was systematically investigated, the conversion of CO_2 with epoxides, propargyl alcohols and amines using ILs was critically evaluated, and the significant advantages in the fixation and conversion of CO_2 using the ILs were demonstrated compared to the conventional absorbents and the catalytic systems without ILs, This research progress may finally lead to building of an in situ fixation-conversion process of CO_2 with ILs, If so, we are neat an epoch of the fixation and utilization of CO_2, although there is obviously a long way to go for us to achieve such a goal.
机译:离子液体(ILs)是一种完全由阳离子和阴离子组成的新型绿色介质,由于其独特的特性(如不挥发,可调整的极性,高稳定性等),最近引起了广泛的关注。在这项工作中,总结了使用IL作为吸收剂,催化剂或促进剂固定和转化二氧化碳(CO_2)的最新进展。系统地研究了常规IL和特定任务IL的吸收性能,严格评估了使用IL的环氧化物,炔丙醇和胺类化合物对CO_2的转化率,并证明了与IL相比,固定和转化CO_2的显着优势。传统的吸收剂和没有ILs的催化体系,这项研究进展可能最终导致建立具有ILs的CO_2的原位固定转化过程。如果这样,尽管存在要实现这一目标,显然还有很长的路要走。

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