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A study on the effect of oxidation-reduction reaction on the corrosion of vitrified radioactive waste

机译:氧化还原反应对玻璃化放射性废物腐蚀的影响研究

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Although the glass materials have much better properties (e.g. leachability and mechanical strength) compared to the conventional immobilizing agents (e.g. cement, concrete, etc.), it is reported that the glass dissolution would take place through metal leaching. Therefore, it is necessary to assess the long-term safety of the vitrified LLW in the final geologic disposal repository. Lots of thermodynamic and kinetic glass dissolution models have been developed and proposed. However, most of them have some limitations and uncertainties. The conventional glass dissolution models have often overestimated the long-term dissolution phenomena which can be observed in natural systems.
机译:尽管与常规的固定剂(例如水泥,混凝土等)相比,玻璃材料具有更好的性能(例如浸出性和机械强度),但是据报道,玻璃的溶解将通过金属浸出而发生。因此,有必要评估最终地质处置库中玻璃化低烟废物的长期安全性。已经开发并提出了许多热力学和动力学玻璃溶解模型。但是,它们大多数都有一些局限性和不确定性。传统的玻璃溶解模型经常高估了在自然系统中可以观察到的长期溶解现象。

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