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Progress towards modeling microstructure evolution in polycrystalline films for solar cell applications

机译:在用于太阳能电池的多晶膜中模拟微观结构演变的进展

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Grain morphology has been long considered to be a major factor in the performance and efficiency of photovoltaic devices. Experimental work has demonstrated the effect of average grain size and surface roughness on the control of conversion efficiency. But its statistics and kinetics are not well understood. While much theoretical progress has been made for α-Si by various effective media and Monte Carlo models, the theory of polycrystalline material growth remains primitive. In this paper, a generalized 2D model was developed to predict cell microstructure under fabrication conditions. Growth of Cadmium Telluride was chosen due to its champion efficiency. The current model combines the numerical efficiency and elegance of the level set method to track the macroscopic interface and includes the simplicity of the phase field method to track the natural microstructure evolution for a non-conserved parameter.
机译:长期以来,晶粒形态一直被认为是光伏器件性能和效率的主要因素。实验工作证明了平均晶粒度和表面粗糙度对控制转化效率的影响。但是,它的统计数据和动力学还不太清楚。尽管各种有效的介质和蒙特卡洛模型已为α-Si取得了许多理论上的进步,但多晶材料生长的理论仍然是原始的。在本文中,开发了一个广义的二维模型来预测制造条件下的细胞微观结构。选择碲化镉的生长是由于其高效率。当前模型结合了数值效率和水平集方法的优美性来跟踪宏观界面,并且包括相场法的简单性来跟踪非保守参数的自然微观结构演化。

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