A temperature-dependent, miscible biphasic liquid-liquid reaction system was Investigated for electrochemical synthesis. The reaction system was constructed by mixtures of cyclohexane and some qualified polar organic solvents, enabling the introduction of a wide variety of chemicals as solutes. By using this system, designed less-polar solutes and polar solutes in a one-phase solution were spatially separated by cooling the reaction mixture with the exclusion of the less-polar phase onto the polar, lower-phase solvents. This property of the system could be an Innovative tool for general organic reactions and liquid-phase combinatorial chemistry with many advantages of electrochemical applications, ease of compound separation, and handling.
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