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Corrosion of 304SS in H_2SO_4 Containing Molybdates as Inhibitors

机译:304钼在含钼酸盐缓蚀剂H_2SO_4中的腐蚀

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The electrochemical behavior of 304 stainless steel has been thoroughly investigated in H_2SO_4 as a function of H_2SO_4 concentration, chloride ions concentration, molybdate ions concentrations, and tungstate ions concentration at room temperature. Standard corrosion techniques that have been employed include Tafel measurements, R_p vs. time measurements, cyclic polarizations measurements, and the critical pitting potential measurements. In addition, the EIS technique was used. Initial results indicate that the addition of molybdate and tungstate ions at sufficient concentrations enhances both the resistance to general corrosion and to pitting corrosion in the presence of chloride ions. Based on the polarization and EIS measurements, a mechanism for corrosion inhibition is suggested.
机译:在H_2SO_4中,已根据室温下H_2SO_4浓度,氯离子浓度,钼酸根离子浓度和钨酸根离子浓度对304不锈钢的电化学行为进行了深入研究。已采用的标准腐蚀技术包括Tafel测量,R_p与时间的关系测量,循环极化测量以及临界点蚀电位测量。另外,使用了EIS技术。初步结果表明,以足够的浓度添加钼酸根离子和钨酸根离子,既可以增强对一般腐蚀的抗性,又可以增强存在氯离子的点蚀的抗性。基于极化和EIS测量,提出了一种缓蚀机理。

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