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THERMAL PLASMA SYNTHESIS OF Si-C-N COMPOSITE POWDERS, INFLUENCE F PRECURSOR AND PROCESSING

机译:热血浆合成Si-C-N复合粉末,影响F前体和加工

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Nanoscale Si-C-N composite powders (mean particle size less than 100 nm) were synthesized by a r.f. induction plasma torch. Reactions of S (CH_3)_4 and NH_3 as well as SiH_4, C_2H_4, and NH_3 were studied. The chemical composition as well as the morphology of nanoscale Si-Cn-N composites can be controlled by both processing and precursors, but the influence of processing is stronger. Crystalline phase is mainly b-Sic, but sometimes, a change of the lattice constant suggests a nisults in nanostructured powders, containing b-SiC as well as a-Si_3N_4 and sometimes -Si_3N_4.
机译:纳米级Si-C-N复合粉末(平均粒径小于100nm)由R.F合成。感应等离子体火炬。研究了S(CH_3)_4和NH_3以及SIH_4,C_2H_4和NH_3的反应。化学组成以及纳米级Si-CN-N复合材料的形态可以通过加工和前体来控制,但加工的影响更强。结晶相主要是B-SiC,但有时,晶格常数的变化表明纳米结构粉末中的Nisults,含有B-SiC以及A-Si_3N_4,有时-Si_3N_4。

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