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Synthesis of Inhomogeneous Modified Polycyanurates by Reactive Blending of Bisphenol A Dicyanate Ester and Polyoxypropylene Glycol

机译:双酚酯和聚氧丙烯二醇的反应混合通过双酚和聚氧二乙二醇合成非均匀改性聚氰脲酸酯

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A series of polycyanurate networks (PCN), based on the dicyanate of bisphenol A monomer (DCBA), was synthesized in the presence of different contents of polyoxypropylene glycol (PPG). The formation of very finely divided morphologies with highly interpenetrated phases, i.e. a PCN- rich phase, a mixed phase of PCN/PPG components and a PPG-rich phase was determined. It is supposed that the lowering of the glass transition temperature of modified network matrix at increasing PPG content is due to a) PPG incorporation, b) decrease of the final DCBA conversion and c) the increase of percentage of non-incorporated PPG, which acts as plasticizer.
机译:基于双酚A单体(DCBA)的二氰酸盐的一系列多囊酸网(PCN)在不同氧化丙二醇(PPG)的存在下合成。确定具有高度渗透相的非常细碎的形态,即PCN-富相,PCN / PPG组分的混合相和富含PPG的相。假设改性网络基质的玻璃化转变温度降低在增加PPG含量的情况下是由于a)ppg掺入,b)最终DCBA转化率的降低和c)增加非掺入PPG的百分比,其作用作为增塑剂。

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