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Modeling of electronic charge transport in smectic liquid crystals

机译:近晶液晶电子电荷运输建模

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We have investigated the hole transport in smectic mesophases by Monte Carlo simulation based on a two-dimensional hopping transport in Gaussian-distributed density of states and time-of-flight experiments. We found that their unique carrier transport properties such as non-Poole-Frenkel type of behavior i.e.,field-and-temperature independent mobility, is well explained by the two-dimensional disorder model with a small Gaussian width of 50-60 meV. Furthermore, we found the Pool-Frenkel type of behavior in a biphenyl derivatives and at a low temperature range below ambient temperature in a therthiphene derivative and determined the Gaussian width to be 100~120meV and 50 meV, respectively. We came to a conclusion that the charge carrier transport in smectic mesophases can be explained by a 2-demensional disorder model with a small Gaussian width of the density of states σ, where a value of σ/kT plays important role to determine its behavior at a given temperature.
机译:我们研究了Monte Carlo仿真在高斯分布密度的二维跳跃运输和飞行时间实验中对蒙特卡罗模拟进行了蒙特卡罗模拟的空穴传输。我们发现,它们独特的载流子运输属性,如非Poopole-Frenkel类型的行为,即现场和温度独立的移动性,由二维紊乱模型进行很好的解释,具有50-60mev的小高斯宽度。此外,我们发现双苯基衍生物中的池骨质型行为,并在低于环境温度的低温范围内,在Therthhene衍生物中,分别确定高斯宽度为100〜120mev和50mev。我们得出结论,近晶中酶的电荷载体传输可以通过具有态度σ的密度小的高斯宽度的2-缺失紊乱模型来解释,其中σ/ kt的值起着重要作用以确定其行为给定温度。

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