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Catalytic Enantioselective Synthesis of Planar Chiral Ferrocene Derivatives by Mo-Catalyzed Asymmetric Metathesis

机译：Mo催化的不对称复分解催化对平面手性二茂铁衍生物的催化对映选择性合成

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Planar chiral ferrocenes are important chiral scaffolds in organic and organometallic chemistry, however, their preparation in optically active form is still a challenging problem. Most of non-racemic planar chiral ferrocenes were obtained either by diastereoselective metalation utilizing chiral ortho-directing groups or by optical resolution of racemic compounds. To the best of our knowledge, only a single example of transition-metal-catalyzed induction of ferrocenyl planar chirality was reported so far with modest enantioselectivity.

机译：平面手性纤维素是有机和有机金属化学中的重要手性支架，但是它们在光学活性形式的制剂仍然是一个具有挑战性的问题。大多数非外消旋平面手性偶锰由非对映选择性金属化使用手性右侧引导基团或通过外消旋化合物的光学分辨率获得。据我们所知，到目前为止，仅报告了迄今为止，仅报告了迄今为止的过渡金属催化诱导的二氧化金属催化诱导的诱导。

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《Symposium on Organometallic Chemistry》|2006年||共1页
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Masamichi Ogasawara; Susumu Watanabe; Kiyohiko Nakajima;
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Catalytic Enantioselective Synthesis of Planar Chiral Ferrocene Derivatives by Mo-Catalyzed Asymmetric Metathesis

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