Reactions of Secondary Phosphine with Various Mononuclear Platinum(II) Complexes

机译：二次膦与各种单核铂（II）复合物的反应

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There have been a number of reports on the syntheses and reactivity of mononuclear platinum(II) complexes with tertiary phosphine ligands. In particular, mononuclear platinum(II) complexes with tertiary phosphine ligands have been studied by many research groups and, for example, syntheses and structures of the platinum-acetylide complexes, trans-[Pt(Ar~1C≡C)(Ar~2C≡C)(PPh3)2] (Ar~1 = Ph, Ar2 = C6H4NO2-4; Ar~1 = Ar~2 = C6H4NH2-4) were reported recently. On the other hand, arylboronic acids have been employed as a convenient source of aryl groups in synthetic organic reactions catalyzed by Pd, Rh, Ni and Pt complexes.

机译：有许多关于单核铂（II）复合物的合成和反应性与叔膦配体的合成和反应性。特别地，已经通过许多研究组研究了具有叔膦配体的单核铂（II）络合物，例如，铂 - 乙酰化络合物的合成和结构，反式 - [Pt（Ar〜1Cly）（Ar〜2C ≡C）（PPH3）2]（Ar〜1 = pH，AR2 = C6H4NO2-4;最近报道了Ar〜1 = Ar〜2 = C6H4NH2-4）。另一方面，已经使用芳基硼酸作为Pd，Rh，Ni和Pt络合物催化的合成有机反应中的方便芳基芳基来源。

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《Symposium on Organometallic Chemistry》|2007年||共1页
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Masaki Kakeya; Kohtaro Osakada;
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1. Complexes derived from the reactions of diphenylphosphinoacetic acid. Part 4. Mononuclear complexes of Rh(I), Ir(I) and Ir(III) and some related chemistry involving the diphenyl(2,6-dimethylphenyl)-phosphine ligand [J] . Kuang SM., Edwards DA., Fanwick PE., Inorganica Chimica Acta . 2003,第0期

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2. Dialkyl- and diaryl-platinum(II) complexes with secondary phosphines: Preparation, structure and thermal reaction giving the metallopolymer [J] . Kakeya Masaki, Tanabe Makoto, Nakamura Yoshiyuki, Journal of Organometallic Chemistry . 2009,第14期

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4. Reactions of Secondary Phosphine with Various Mononuclear Platinum(II) Complexes [C] . Masaki Kakeya, Kohtaro Osakada Symposium on Organometallic Chemistry . 2007

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5. Mechanistic Studies of Oxygen Activation and Atom Transfer Reactions with Mononuclear Vanadium(III), Iron(II), and Palladium(0) Complexes. [D] . Palluccio, Taryn D. 2015

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6. Correctionto Iridium(III) Hydrido N-HeterocyclicCarbene–Phosphine Complexes as Catalysts in Magnetization TransferReactions [O] . Marianna Fekete, Oliver W. Bayfield, Simon B. Duckett, -1

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8. Dialkylamino Phosphorus Metal Carbonyls. 1. Mononuclear Derivatives from Reactions of Bis(diisopropylamino)phosphine with Metal Carbonyls [R] . King, R. B., Wu, W. K. 1986

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Reactions of Secondary Phosphine with Various Mononuclear Platinum(II) Complexes

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