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Acid Promoted New Carbon-Hydrogen Bond Cleavage Mechanism in 2-Allylphenoxoruthenium(II) Complex

机译：酸促进2-烯丙基氧氧氧氧氧鎓（II）复合物中的新型碳 - 氢粘合裂解机制

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C-H Bond cleavage reactions by ruthenium complexes have been extensively studied due to their potential utility in organic synthesis. One of the important factors for C-H bond cleavage reaction is prior coordination or binding through an anchoring group to bring the unactivated C-H bond in proximity to the ruthenium center. Recently, we found that Bronsted acids effectively promoted intramolecular C-H bond cleavage reaction of RuCp[OC6H4(CH2CH=CH2-2)-K~1O](PPh3)2 (1), leading to RuCp[CH2CHCH(C6H4OH-2)-η~3C,C',C"](PPh3) (3) under ambient conditions. Herein we report a new type acid-promoted C-H bond cleavage reaction, that involvs a 6 membered transition-state concerning two acid molecules.

机译：由于它们在有机合成中的潜在效用，钌配合物的C-H键裂解反应已经过度研究。 C-H键裂解反应的重要因素之一是通过锚定基团的结合或结合，以使未激活的C-H键与钌中心的邻近。最近，我们发现伪造酸有效地促进了RUCP [OC6H4（CH2CH = CH2-2）-K〜1O]（PPH3）2（1）的分子内CH键裂解反应，所述RUCP [CH 2 CHCH（C6H4OH-2）-η在环境条件下〜3C，C'，C“]（PPH3）（3）。在本文中，我们报告了一种新型酸促进的CH键切割反应，其涉及关于两个酸分子的6元转变状态。

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《Symposium on Organometallic Chemistry》|2008年||共1页
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Toshinori Kuga; Nobuyuki Komine; Masafumi Hirano;
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1. Acid-promoted sp3 C-H bond cleavage in a series of (2-allylphenoxo) ruthenium(II) complexes. Mechanistic insight into the aryloxo-acid interaction and bond cleavage reaction [J] . Hirano M., Murakami M., Kuga T., Organometallics . 2012,第1期

机译：酸促进的sp3 C-H键在一系列（2-烯丙基苯氧基）钌（II）配合物中的裂解。机械了解芳基氧酸相互作用和键裂解反应
2. Acid-promoted sp3 C-H bond cleavage in a series of (2-allylphenoxo) ruthenium(II) complexes. Mechanistic insight into the aryloxo-acid interaction and bond cleavage reaction [J] . Hirano M., Murakami M., Kuga T., Organometallics . 2012,第1期

机译：酸促进的sp3 C-H键在一系列（2-烯丙基苯氧基）钌（II）配合物中的裂解。机械了解芳基氧酸相互作用和键裂解反应
3. Carbon-hydrogen bond cleavage reaction in 5-coordinate bis(2,6- dimethylbenzenethiolato)ruthenium(II) complexes [J] . Hirano M., Togashi S., Ito M., Organometallics . 2010,第14期

机译：五配位双（2,6-二甲基苯硫基）钌（II）配合物的碳氢键裂解反应
4. Acid Promoted New Carbon-Hydrogen Bond Cleavage Mechanism in 2-Allylphenoxoruthenium(II) Complex [C] . Toshinori Kuga, Nobuyuki Komine, Masafumi Hirano Symposium on Organometallic Chemistry . 2008

机译：酸促进2-烯丙基氧氧氧氧氧鎓（II）复合物中的新型碳 - 氢粘合裂解机制
5. Density functional theory investigation into mechanisms of metal ion-promoted and base-promoted phosphorothioate cleavage reactions and Lanthanide ion catalysts for kinetic resolution of amino acid esters. [D] . Maxwell, Christopher Ian. 2012

机译：密度泛函理论研究金属离子促进和碱促进的硫代磷酸酯裂解反应机理以及镧系元素离子催化剂用于氨基酸酯的动力学拆分。
6. Biocatalytic Carbon-Hydrogen and Carbon-Fluorine Bond Cleavage through Hydroxylation Promoted by a Histidyl-Ligated Heme Enzyme [O] . Yifan Wang, Ian Davis, Inchul Shin, -1

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7. Carbon-Oxygen and Carbon-Hydrogen Bond Cleavage Reactions of ortho-Substituted Phenols by Ruthenium(II) Complexes [O] . -1

机译：钌（II）配合物的碳 - 氧和碳 - 氢粘合脱落反应邻苯酚
8. Mechanism of Oxidative Addition of Cyclopentadienyl-Rhodium Complexes to Carbon-Hydrogen and Carbon-Carbon Bonds [R] . Periana-Pillai, R. A. 1985

机译：环戊二烯基 - 铑配合物氧化加成碳氢和碳 - 碳键的机理

Acid Promoted New Carbon-Hydrogen Bond Cleavage Mechanism in 2-Allylphenoxoruthenium(II) Complex

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