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Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes

机译：通过过渡金属催化的碳骨架施工碳骨架和立体选择性加入碳 - 硫醇键与炔烃和艾伦

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Transition metal-catalyzed addition of carbon-heteroatom bonds (represented as "C" and "E", respectively) to alkynes or allenes is one of the most promising routes to highly substituted alkenes. Since the introduced heteroatom functionality can be subjected to further manipulation, products would be useful building blocks in organic synthesis. Here we wish to report novel methods for the construction of carbon skeletons by addition of carbon-chalcogen (sulfur or selenium) bonds to alkynes or allenes: i) Pd(0) or Pt(0)-catalyzed intramolecular carbochalcogenation of alkynes giving rise to various carbocycles having an exo-methylene moiety, ii) Pd(0)-catalyzed inter- and intramolecular acylselenation of allenes leading to the regioselective formation of functionalized allyl selenides.

机译：过渡金属催化的碳 - 杂原子键（分别为“C”和“E”）分别为炔或丙烯醚是最有前途的高度取代烯烃的途径之一。由于介绍的杂原子功能可以进行进一步的操纵，因此产品将是有机合成中有用的结构块。在这里，我们希望通过将碳 - 硫曲根（硫或硒）键加入炔或烯烷烃：I）Pd（0）或Pt（0） - 催化分子内碳化碳化碳化碳基催化剂的碳胆碱（硫化物或硒）键来报告碳骨架的新方法具有外甲基部分，II）Pd（0）的各种碳缩乳 - 催化和分子内酰基硅烷化，导致官能化烯丙基硒化物的区域选择性形成。

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《Symposium on Organometallic Chemistry》|2008年||共1页
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Masashi Tovofuku; Erika Murase; Atsushi Okada;
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中图分类元素有机化合物;
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1. Regio- and stereoselective addition of perfluoroalkyl iodides to allenes conjugated with carbon-oxygen or phosphorus-oxygen double bonds [J] . Mei YQ, Liu JT, Liu ZJ Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2007,第5期

机译：全氟烷基碘的区域和立体选择性加成到与碳-氧或磷-氧双键共轭的丙二烯中
2. Transition-metal-catalyzed cleavage of carbon-selenium bond and addition to alkynes and allenes [J] . Fujiwara S, Toyofuku M, Kuniyasu H, Pure and Applied Chemistry . 2010,第3期

机译：过渡金属催化的碳-硒键裂解并加成炔烃和烯丙基
3. Synthesis of Multisubstituted Olefins through Regio- and Stereoselective Addition of Interelement Compounds Having B-Si, B-B, and Cl-S Bonds to Alkynes, and Subsequent Cross-Couplings [J] . Iwasaki Masayuki, Nishihara Yasushi Chemical record . 2016,第4期

机译：通过区域和立体选择性将具有B-Si，B-B和Cl-S键的元素化合物与炔烃进行立体选择性加成反应，以及随后的交叉偶联反应
4. Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes [C] . Masashi Tovofuku, Erika Murase, Atsushi Okada Symposium on Organometallic Chemistry . 2008

机译：通过过渡金属催化的碳骨架施工碳骨架和立体选择性加入碳 - 硫醇键与炔烃和艾伦
5. Transition metal-catalyzed tandem carbon-oxygen and carbon-carbon bond forming reactions of alkynes in (1) the addition-cyclization of carboxylic acids with 1,6-diynes and in (2) the total synthesis of frondosin B. [D] . Goble, Stephen D. 2006

机译：炔烃的过渡金属催化串联碳-氧和碳-碳键形成反应在（1）羧酸与1,6-二炔的加成环化中和（2）frondosin B的总合成中。
6. Transition Metal-Catalyzed C–H Bond Addition to Carbonyls Imines and Related Polarized π-Bonds [O] . Joshua R. Hummel, Jeffrey A. Boerth, Jonathan A. Ellman -1

机译：过渡金属催化的C–H键与羰基亚胺和相关极化π键的结合
7. Palladium-catalyzed highly regio- and stereoselective addition of organoboronic acids to allenes in the presence of AcOH [O] . Ma SM, Jiao N, Ye LW, 2003

机译：在AcOH存在下钯催化的有机硼酸向烯基的高度区域和立体选择性加成

Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes

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