首页> 外文会议>Biennial ASME Conference on Engineering Systems Design and Analysis >PHASE INTERACTIONS IN MONOCLINIC ZIRCONIA REINFORCED HYDROXYLAPATITE BIOCERAMICS
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PHASE INTERACTIONS IN MONOCLINIC ZIRCONIA REINFORCED HYDROXYLAPATITE BIOCERAMICS

机译:单醚氧化锆增强羟基磷灰石生物陶瓷的相互作用

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Hydroxylapatite composites with pure zirconia were prepared with pressureless air sintering and hot pressing for 1 hour at different temperatures between 900°C and 1300°C. The interaction between the phases was monitored with XRD and thermal analysis. At sintering temperatures higher than 1000°C, an apparent Ca diffusion occurred from hydroxylapatite to pure zirconia phase and changed its structure from monoclinic to tetragonal/cubic. In the mean time, hydroxylapatite decomposed and formed tricalcium phosphate. Also, a reaction was occurred at 1220°C between hydroxylapatite and zirconia phase forming CaZrO{sub}3. The existence of air in the processing environment increased the reactivity between hydroxylapatite and zirconia.
机译:用纯氧化锆的羟基磷灰石复合材料用无压空气烧结和热压在900℃和1300℃之间的不同温度下的热压1小时。通过XRD和热分析监测相之间相的相互作用。在高于1000℃的烧结温度下,从羟基磷灰石发生明显的Ca扩散到纯氧化锆相,并改变其从单斜晶型到四方/立方的结构。在平均的时间内,羟基磷灰石分解并形成磷酸三钙。此外,在1220℃之间形成反应,与羟基磷灰石和氧化锆相形成Cazro {sub} 3。加工环境中的空气存在增加了羟基磷灰石和氧化锆之间的反应性。

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