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Inspiration from Karl A. Gschneidner, Jr.: Rare Earth containing Zintl Phases and their Thermoelectric and Magnetic Properties

机译：Karl A. Gschneidner，JR的灵感.:含有ZINTL相的稀土及其热电和磁性

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In the past decade, Zintl phases have seen a significant increase in research because they provide a class of compounds where one can easily correlate the structure and bonding to physical properties. Zintl phases are a subset of the intermetallics where the structure can be understood using simple electron counting rules and in general, the stoichiometry is consistent with an electron precise semiconductor.2 Zintl phases are made up of electropositive elements that donate their electrons to the more electronegative metalloids to form isolated anions, polyhedra, or extended structures. The structures can be described via a combination of ionic bonding between the cations and anions and covalent bonding for polyhedra or extended structures. In the case of isolated anions, the element can be considered to complete its octet.

机译：在过去的十年中，Zintl阶段已经看出了研究的显着增加，因为它们提供了一类可以容易地将结构与物理性能相关的化合物。 Zintl相是金属间金属间的子集，其中结构可以使用简单的电子计数规则来理解，并且通常，化学计量是一致的，电子精确半导体2 Zintl相位由赋予其电子的电力元素达到更电力的电气元件金属体形成隔离阴离子，多面体或延长的结构。结构可以通过阳离子和阴离子之间的离子键合和用于多面体或延长结构的共价键合来描述。在隔离阴离子的情况下，可以认为元件完成其八位字节。

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《Rare Earth Research Conference》|2019年|209p|共1页
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Kasey P. Devlin; Nasrin Kazem; Julia Zaikina;
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1. Magnetic Properties and Negative Colossal Magnetoresistance of the Rare Earth Zintl phase EuIn(2)AS(2) [J] . Goforth AM, Klavins P, Fettinger JC, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第23期

机译：稀土Zintl相EuIn（2）AS（2）的磁性能和负巨磁电阻
2. Magnetism and Negative Magnetoresistance of Two Magnetically Ordering, Rare-Earth-Containing Zintl phases with a New Structure Type: EuGa2Pn2 (Pn = P, As) [J] . Andrea M. Goforth, Hakon Hope, Cathie L. Condron Chemistry of Materials: A Publication of the American Chemistry Society . 2009,第19期

机译：具有新结构类型的两个磁序含稀土的Zintl相的磁性和负磁阻：EuGa2Pn2（Pn = P，As）
3. Magnetism and Negative Magnetoresistance of Two Magnetically Ordering, Rare-Earth-Containing Zintl phases with a New Structure Type: EuGa2Pn2 (Pn = P, As) [J] . Andrea M. Goforth, Hakon Hope, Cathie L. Condron Chemistry of Materials: A Publication of the American Chemistry Society . 2009,第19期

机译：具有新结构类型的两个磁序含稀土的Zintl相的磁性和负磁阻：EuGa2Pn2（Pn = P，As）
4. Inspiration from Karl A. Gschneidner, Jr.: Rare Earth containing Zintl Phases and their Thermoelectric and Magnetic Properties [C] . Kasey P. Devlin, Nasrin Kazem, Julia Zaikina Rare Earth Research Conference . 2019

机译：Karl A. Gschneidner，JR的灵感.:含有ZINTL相的稀土及其热电和磁性
5. Ternary and quaternary pnictides of alkali, alkaline- and rare-earth metals and group 12 metals: Size and electronic effects in Zintl phases [D] . Saparov, Bayrammurad 2011

机译：碱金属，碱金属和稀土金属以及第12组金属的三元和四元锡：Zintl相的尺寸和电子效应
6. PNAS Plus: Higher thermoelectric performance of Zintl phases (Eu0.5Yb0.5)1−xCaxMg2Bi2 by band engineering and strain fluctuation [O] . Jing Shuai, Huiyuan Geng, Yucheng Lan, 2016

机译：PNAS Plus：通过能带工程和应变波动Zintl相（Eu0.5Yb0.5）1-xCaxMg2Bi2具有更高的热电性能
7. Magnetism and Negative Magnetoresistance of Two Magnetically Ordering, Rare-Earth-Containing Zintl phases with a New Structure Type: EuGa2Pn2 (Pn = P, As) [O] . Andrea M. Goforth, Håkon Hope, Cathie L. Condron, 2009

机译：磁性排序的磁性和负磁阻，具有新的结构类型：Euga2PN2（PN = P，AS），磁排序含稀土的Zintl相位

Inspiration from Karl A. Gschneidner, Jr.: Rare Earth containing Zintl Phases and their Thermoelectric and Magnetic Properties

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