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Synthesis, crystal structure, thermal and nonlinear optical properties of new metal-organic single crystal: Tetrabromo (piperazinium) zincate (II) (TBPZ)

机译：新金属 - 有机单晶的合成，晶体结构，热和非线性光学性能：Tetrabromo（Piperazinium）锌酸锌（II）（TBPZ）

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Tetrabromo (piperazinium) zincate, a new metal-organic crystal has been synthesized and its single crystal grown by slow evaporation method. The grown crystal has characterized by structural, spectral, thermal, linear and nonlinear optical properties. Single crystal X-ray diffractions study reveals that grown crystal belongs to orthorhombic crystal system with space group P2_12_12_1. The presence of functional groups is identified by FT-IR spectral analysis. Thermal stability of the crystal was ascertained by TG-DTA measurement. The second order harmonic generation efficiency was measured using Kurtz and Perry technique and it was found to be 1.5 times that of KDP.

机译：四溴吡喃（Piperazinium）锌酸锌，已经合成了一种新的金属 - 有机晶体，其单晶通过缓慢蒸发方法种植。生长的晶体的特征在于结构，光谱，热，线性和非线性光学性能。单晶X射线衍射研究表明，生长的晶体属于具有空间组P2_12_12_1的正交晶体系统。通过FT-IR光谱分析鉴定了官能团的存在。通过TG-DTA测量确定晶体的热稳定性。使用Kurtz和Perry技术测量二阶谐波产生效率，发现KDP的1.5倍。

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《DAE Solid State Physics Symposium》|2018年|various paging|共4页
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K. Boopathi; S. Moorthy Babu; P. Ramasamy;
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Synthesis, crystal structure, thermal and nonlinear optical properties of new metal-organic single crystal: Tetrabromo (piperazinium) zincate (II) (TBPZ)

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